Renewable -Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand

Bo Liu; Bao-yu Han; Chun-ling Zhang; Shi-hui Li; Guang-ping Sun; Dong-mei Cui

doi:10.1007/s10118-015-1629-8

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Renewable -Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand

PAPER | Updated：2021-06-21

- Renewable -Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand
- Renewable β-Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand
- Chinese Journal of Polymer Science 2015年33卷第5期页码：792-796
- Affiliations：
  
  a.Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun 130022, China
  b.Changchun Vocational Institute of Technology, Changchun 130000, China
  c.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  **Shi-hui Li (李世辉), E-mail: shihui-li@ciac.ac.cn
  Guang-ping Sun (孙广平), E-mail: sungp@jlu.edu.cn
  Dong-mei Cui (崔冬梅), E-mail: dmcui@ciac.ac.cn
- Funds：
  
  National Natural Science Foundation of China(21104074;51321062)
- DOI：10.1007/s10118-015-1629-8
  中图分类号：
- 收稿：2014-12-21，
  
  修回：2015-01-16，
  
  录用：2015-01-17，
  
  纸质出版：2015-05
- Accepted：
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Bo Liu, Bao-yu Han, Chun-ling Zhang, 等. Renewable -Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand[J]. Chinese Journal of Polymer Science, 2015,33(5):792-796.

Bo Liu, Bao-yu Han, Chun-ling Zhang, et al. Renewable β-Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand[J]. Chinese Journal of Polymer Science, 2015, 33(5): 792-796. DOI: 10.1007/s10118-015-1629-8.
Bo Liu, Bao-yu Han, Chun-ling Zhang, 等. Renewable -Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand[J]. Chinese Journal of Polymer Science, 2015,33(5):792-796. DOI： 10.1007/s10118-015-1629-8.

Bo Liu, Bao-yu Han, Chun-ling Zhang, et al. Renewable β-Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand[J]. Chinese Journal of Polymer Science, 2015, 33(5): 792-796. DOI: 10.1007/s10118-015-1629-8. DOI：

摘要

Abstract

-Imidophosphonamido ligated lutetium alkyl complex (NPN

Dipp

)Lu(CH

SiMe

)

(THF) (NPN

Dipp

= Ph

P(NC

-2

) with the activation of Al

and [Ph

C][B(C

)

] exhibited high catalytic activity

medium syndio- (rr = 66%) but remarkably high 3

4-regioselectivity for the polymerization of

-myrcene (MY). In sharp contrast

high isotactic 3

4-polymyrcene (PMY) (mm = 95%) was obtained by the precursor (NPN

)Lu(CH

SiMe

)

(THF) (NPN

= PPh

(NC

-2

)(NC

-Et-2)) with less bulky substituents on the

-aryl ring.

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