Synthesis and characterization of heterocyclic functionalized polymers by click reaction: Preparation of magnetic nanocomposites and studies on their thermal, mechanical, photophysical and metal ions removal properties

Mousa Ghaemy; Sahar Shabzendedar; Mehdi Taghavi

doi:10.1007/s10118-015-1583-5

Your Location：

Home >

Browse articles >

Synthesis and characterization of heterocyclic functionalized polymers by click reaction: Preparation of magnetic nanocomposites and studies on their thermal, mechanical, photophysical and metal ions removal properties

PAPER | Updated：2022-01-17

- Synthesis and characterization of heterocyclic functionalized polymers by click reaction: Preparation of magnetic nanocomposites and studies on their thermal, mechanical, photophysical and metal ions removal properties
- Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties
- Chinese Journal of Polymer Science 2015年33卷第2期页码：301-317
- Affiliations：
  
  1.Polymer Chemistry Research Laboratory, Department of Chemistry, University of Mazandaran, Babolsar, 47416-95447, I.R. Iran
- Author bio：
  
  *Mousa Ghaemy, E-mail: ghaemy@umz.ac.ir
- Funds：
- DOI：10.1007/s10118-015-1583-5
  中图分类号：
Scan for full text
Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and characterization of heterocyclic functionalized polymers by click reaction: Preparation of magnetic nanocomposites and studies on their thermal, mechanical, photophysical and metal ions removal properties[J]. Chinese Journal of Polymer Science, 2015,33(2):301-317.

Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties[J]. Chinese Journal of Polymer Science, 2015,33(2):301-317.
Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and characterization of heterocyclic functionalized polymers by click reaction: Preparation of magnetic nanocomposites and studies on their thermal, mechanical, photophysical and metal ions removal properties[J]. Chinese Journal of Polymer Science, 2015,33(2):301-317. DOI： 10.1007/s10118-015-1583-5.

Mousa Ghaemy, Sahar Shabzendedar, Mehdi Taghavi. Synthesis and Characterization of Heterocyclic Functionalized Polymers by Click Reaction: Preparation of Magnetic Nanocomposites and Studies on Their Thermal, Mechanical, Photophysical and Metal Ions Removal Properties[J]. Chinese Journal of Polymer Science, 2015,33(2):301-317. DOI： 10.1007/s10118-015-1583-5.

摘要

Abstract

This work reports synthesis and characterization of heterocyclic functionalized polymers, poly(triazole-ether-imidazole) s (PTAEI), from a dialkyne-terminated compound, 3-(4,5-bis(4-(propargyloxy)phenyl)-1H-imidazol-2-yl)-9-ethyl-9H-carbazole, by using click reaction. PTAEIs were characterized and their properties such as solubility, thermal, mechanical, photophysical and metal ions adsorption were investigated. These polymers had weight average molar masses (,M,w,) in the range of 19100-26700 g/mol, exhibited excellent solubility in polar aprotic solvents and formed low-colored flexible thin films by solution casting method. They exhibited good thermal stability with glass transition temperatures (,T,g,) between 160 °C and 211 °C and 10% weight loss temperatures (T10%) in the range of 308-426 °C. Nanocomposites of PTAEIs with epoxide-terminated Fe,3,O,4, showed that strong interfacial interaction between inorganic particles and the polymer matrix contributed to the enhanced thermal and mechanical properties. The photoluminescence intensity of the PTAEIs increased and the spectra red shifted with increasing Fe,3,O,4, content. The PTAEIs and nanocomposites were tested for their extraction capability of metal ions from aqueous solutions either individually or in the mixture.

关键词

Keywords

Click chemistryHeterocylic polymerPoly(triazole-ether-imidazole)Magnetic nanocompositeMetal ion removal

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Synthesis of Self-assemble pH-responsive Cyclodextrin Block Copolymer for Sustained Anticancer Drug Delivery

Thermal and Redox Dual Responsive Poly (L-glutamate) with Oligo (ethylene glycol) Side-chains

Synthesis, Curing and Properties of Poly (phthalazione ether sulfone ketone) Copolymers Crosslinked by Click Chemistry

Hydrogels of Chemically Cross-linked and Organ-metallic Complexed Interpenetrating PEG Networks

Synthesis, Characterization and Phase Behaviors of Polypeptides Bearing Biphenyl Mesogens and Oligo-Ethylene-Glycol Tails