Preparation of ligand free Au NPs/PPV composites with high stability and photo-electric response

Fei Zhai; Hao-tong Wei; Su-mei Zhan; Gan Jin; Bai Yang; Hai-zhu Sun; Zong-hao Huang

doi:10.1007/s10118-015-1574-6

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Preparation of ligand free Au NPs/PPV composites with high stability and photo-electric response

PAPER | Updated：2022-01-17

- Preparation of ligand free Au NPs/PPV composites with high stability and photo-electric response
- Preparation of Ligand Free Au NPs/PPV Composites with High Stability and Photo-electric Response
- Chinese Journal of Polymer Science 2015年33卷第2期页码：215-223
- Affiliations：
  
  a.College of Chemistry, Northeast Normal University, Changchun 130024, China
  b.State Key Laboratory of Supramolecular Structure & Materials, College of Chemistry, Jilin University, Changchun 130012, China
- Author bio：
  
  † These authors contributed equally to this work.
  **Hai-zhu Sun (孙海珠), E-mail: sunhz335@nenu.edu.cn
  Zong-hao Huang (黄宗浩), E-mail: huangzh295@nenu.edu.cn
- Funds：
  
  National Natural Science Foundation of China(51433003;21221063;91123031);Science Technology Program of Jilin Province(201201064;20130204025GX);the Major State Basic Research Development Program(2014CB643503)
- DOI：10.1007/s10118-015-1574-6
  中图分类号：
- 收稿：2014-04-03，
  
  修回：2014-05-07，
  
  录用：2014-05-20，
  
  纸质出版：2015-02
- Accepted：
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Fei Zhai, Hao-tong Wei, Su-mei Zhan, 等. Preparation of ligand free Au NPs/PPV composites with high stability and photo-electric response[J]. Chinese Journal of Polymer Science, 2015,33(2):215-223.

Fei Zhai, Hao-tong Wei, Su-mei Zhan, et al. Preparation of Ligand Free Au NPs/PPV Composites with High Stability and Photo-electric Response[J]. Chinese Journal of Polymer Science, 2015, 33(2): 215-223.
Fei Zhai, Hao-tong Wei, Su-mei Zhan, 等. Preparation of ligand free Au NPs/PPV composites with high stability and photo-electric response[J]. Chinese Journal of Polymer Science, 2015,33(2):215-223. DOI： 10.1007/s10118-015-1574-6.

Fei Zhai, Hao-tong Wei, Su-mei Zhan, et al. Preparation of Ligand Free Au NPs/PPV Composites with High Stability and Photo-electric Response[J]. Chinese Journal of Polymer Science, 2015, 33(2): 215-223. DOI： 10.1007/s10118-015-1574-6.

摘要

Abstract

A novel kind of ligand free aurum nanoparticles (Au NPs)/poly(p-phenylene-vinylene) (PPV) composites was prepared via a simple approach. Although there were no ligands coating on the surface of the Au NPs

the Au NPs/PPV precursor composite exhibited excellent stability that no obvious variance was found as long as 6 months at ~4 ℃ in aqueous and alcohol mixed solutions. This was attributed to the strong interaction between Au NPs and PPV precursor

which was further strengthened after heat transformation. Fourier transform infrared (FTIR) and Raman spectra showed the interaction between benzene ring in PPV and Au NPs led to the part transformation of the sp

hybrid orbital into the sp

one during the composite formation. As a result

the photoluminescence (PL) life time of PPV in the composite was longer than that of pure PPV. The Au NPs/PPV composite exhibited good photo-electric response

indicating their potential application in the area of the photoelectric conversion devices.

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