Synergistic Effect of Phosphite with Fullerene C60 and Fullerenol C60(OH)24 as Antioxidants in Polypropylene

Jian-wei Zhang; Hua-yi Li; Hang Fan; Yu Zhang; Li Jiang; Chun-ru Wang; Chao Ma; Yu-jun Liu

doi:10.1007/s10118-014-1525-7

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Synergistic Effect of Phosphite with Fullerene C60 and Fullerenol C60(OH)24 as Antioxidants in Polypropylene

PAPER | Updated：2021-06-21

- Synergistic Effect of Phosphite with Fullerene C60 and Fullerenol C60(OH)24 as Antioxidants in Polypropylene
- Synergistic Effect of Phosphite with Fullerene C₆₀ and Fullerenol C₆₀(OH)₂₄ as Antioxidants in Polypropylene
- Chinese Journal of Polymer Science 2014年32卷第10期页码：1357-1362
- Affiliations：
  
  a.Beijing Key Laboratory of Forest Food Processing and Safety, College of Biological Sciences and Biotechnology, Beijing Forestry University, Beijing 100083, China
  b.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  c.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Nanostucture and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  **Hua-yi Li (李化毅), E-mail: lihuayi@iccas.ac.cn
  Yu-jun Liu (刘玉军), E-mail: yjliubio@163.com
- Funds：
  
  Fundamental Research Funds for the Central Universities, China(TD2012-03)
- DOI：10.1007/s10118-014-1525-7
  中图分类号：
- 收稿：2013-12-13，
  
  修回：2014-01-28，
  
  录用：2014-02-10，
  
  纸质出版：2014-10
- Accepted：
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Jian-wei Zhang, Hua-yi Li, Hang Fan, 等. Synergistic Effect of Phosphite with Fullerene C60 and Fullerenol C60(OH)24 as Antioxidants in Polypropylene[J]. Chinese Journal of Polymer Science, 2014,32(10):1357-1362.

Jian-wei Zhang, Hua-yi Li, Hang Fan, et al. Synergistic Effect of Phosphite with Fullerene C₆₀ and Fullerenol C₆₀(OH)₂₄ as Antioxidants in Polypropylene[J]. Chinese Journal of Polymer Science, 2014, 32(10): 1357-1362. DOI: 10.1007/s10118-014-1525-7.
Jian-wei Zhang, Hua-yi Li, Hang Fan, 等. Synergistic Effect of Phosphite with Fullerene C60 and Fullerenol C60(OH)24 as Antioxidants in Polypropylene[J]. Chinese Journal of Polymer Science, 2014,32(10):1357-1362. DOI： 10.1007/s10118-014-1525-7.

Jian-wei Zhang, Hua-yi Li, Hang Fan, et al. Synergistic Effect of Phosphite with Fullerene C₆₀ and Fullerenol C₆₀(OH)₂₄ as Antioxidants in Polypropylene[J]. Chinese Journal of Polymer Science, 2014, 32(10): 1357-1362. DOI: 10.1007/s10118-014-1525-7. DOI：

摘要

Abstract

Polypropylene samples with fullerene C

fullerenol C

(OH)

1010

/168

-OH/168 and 1010/168 as antioxidants were prepared by extrusions. MFR

TGA and OIT of all the samples were tested. According to the results of MFR

during the melt extrusion

fullerene showed excellent stability effect on PP. The antioxidative ability of fullerene was comparable to the traditional antioxidant 1010. The antioxidative ability of fullerenol was not significant in the first extrusion and it accelerated the degradation of PP in the second and the third extrusions. TGA and OIT tests showed that the stability effects of fullerene and fullerenol were slightly lower than antioxidant 1010. In the first time

antioxidant 168 was reported to show great synergistic effects with fullerene and fullerenol as antioxidants

which sussested a simple way to enhance the antioxidative abilities of fullerene and fullerenol.

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