Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers

S. Venkatesan; B. Ranjithkumar; S. Rajeshkumar; K. Anver Basha

doi:10.1007/s10118-014-1515-9

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Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers

PAPER | Updated：2021-06-21

- Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers
- Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers
- Chinese Journal of Polymer Science 2014年32卷第10期页码：1373-1380
- Affiliations：
  
  a.P.G. & Research Department of Chemistry, C. Abdul Hakeem College, Hakeem Nagar, Melvisharam-632509, Tamil Nadu, India
  b.Department of Biochemistry, Adhiparasakthi College of Arts and Science, Kalavai-632506, Vellore Dt, TamilNadu, India
- Author bio：
  
  *K. Anver Basha, E-mail: anverbasha.etal@rediffmail.com
- Funds：
- DOI：10.1007/s10118-014-1515-9
  中图分类号：
- 收稿：2013-12-16，
  
  修回：2014-04-09，
  
  录用：2014-04-14，
  
  纸质出版：2014-10
- Accepted：
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S. Venkatesan, B. Ranjithkumar, S. Rajeshkumar, 等. Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers[J]. Chinese Journal of Polymer Science, 2014,32(10):1373-1380.

S. Venkatesan, B. Ranjithkumar, S. Rajeshkumar, et al. Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers[J]. Chinese Journal of Polymer Science, 2014, 32(10): 1373-1380.
S. Venkatesan, B. Ranjithkumar, S. Rajeshkumar, 等. Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers[J]. Chinese Journal of Polymer Science, 2014,32(10):1373-1380. DOI： 10.1007/s10118-014-1515-9.

S. Venkatesan, B. Ranjithkumar, S. Rajeshkumar, et al. Synthesis, Characterization, Thermal Stability and Antibacterial Activity of Coumarin Based Methacrylate Copolymers[J]. Chinese Journal of Polymer Science, 2014, 32(10): 1373-1380. DOI： 10.1007/s10118-014-1515-9.

摘要

Abstract

Monomer of 7-methacryloyloxy-4-methylcoumarin (MAOMC) was synthesized and characterized by FTIR

H-NMR and

C-NMR spectroscopy. Copolymers of MAOMC with butoxyethylmethacrylate (BOEMA) at different feed compositions were prepared by free radical solution polymerization at (70 ± 1) ℃ in ethylmethylketone (EMK) using benzyl peroxide (BPO) as an initiator. The copolymers were characterized by FTIR and

H-NMR spectroscopy. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of the copolymers showed moderate thermal stability and higher

values. Gel permeation chromatography (GPC) was used to find out the molecular weights of the different copolymers. Antibacterial activities of the copolymers were also investigated against the selected pathogenic bacteria's. The antibacterial activity of the copolymer increases as the MAOMC content increases in the copolymer. This shows that coumarin moiety plays a very important role in the antibacterial activity.

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