Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene)：Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid

Li-ping Wu; Long Zhang; Li-min Lu; Xue-min Duan; Jing-kun Xu; Tao Nie

doi:10.1007/s10118-014-1484-z

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Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene)：Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid

Updated：2021-06-21

- Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene)：Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid
- Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene): Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid
- Chinese Journal of Polymer Science 2014年32卷第8期页码：1019-1031
- Affiliations：
  
  a.College of Science, Jiangxi Agricultural University, Nanchang 330045, China
  b.Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
- Author bio：
  
  Li-min Lu (卢丽敏), E-mail: lulimin816@hotmail.com
  **Jing-kun Xu (徐景坤), E-mail: xujingkun@tsinghua.org.cn
- Funds：
  
  National Natural Science Foundation of China(50963002;51073074;51272906;51263010;51302117);Natural Science Foundation of Jiangxi Province(2010GZH0041;20122BAB213007);Jiangxi Provincial Department of Education(GJJ11590;GJJ10678;GJJ13258);Jiangxi Science & Technology Normal University Innovation Fund of Postgraduates(YC2013-X25)
- DOI：10.1007/s10118-014-1484-z
  中图分类号：
- 收稿：2013-11-19，
  
  修回：2014-01-04，
  
  录用：2014-01-28，
  
  纸质出版：2014-08
- Accepted：
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Li-ping Wu, Long Zhang, Li-min Lu, 等. Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene)：Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid[J]. Chinese Journal of Polymer Science, 2014,32(8):1019-1031.

Li-ping Wu, Long Zhang, Li-min Lu, et al. Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene): Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1019-1031.
Li-ping Wu, Long Zhang, Li-min Lu, 等. Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene)：Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid[J]. Chinese Journal of Polymer Science, 2014,32(8):1019-1031. DOI： 10.1007/s10118-014-1484-z.

Li-ping Wu, Long Zhang, Li-min Lu, et al. Graphene Oxide Doped Poly(hydroxymethylated-3,4-ethylenedioxythiophene): Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1019-1031. DOI： 10.1007/s10118-014-1484-z.

摘要

Abstract

A novel graphene oxide doped poly(hydroxymethylated-3

4-ethylenedioxythiophene) (PEDOT-MeOH/GO) composite film was synthesized and utilized as an efficient electrode material for simultaneous detection of rutin and ascorbic acid (AA). PEDOT-MeOH/GO films were synthesized on glassy carbon electrode (GCE) by a facile one-step electrochemical approach and were characterized by scanning electron microscopy

UV-Vis spectroscopy

FTIR spectra and electrochemical methods. Then the PEDOT-MeOH/GO/GCE was applied successfully in the simultaneous detection of rutin and AA. The results showed that the oxidation peak currents of rutin and AA obtained at the PEDOT-MeOH/GO/GCE were much higher than those at the traditional conducting polymer PEDOT/GO/GCE

PEDOT-MeOH/GCE

PEDOT/GCE and bare GCE. Under optimized conditions

the linear ranges for rutin and AA are 20 nmol/L−10 μmol/L and 8 μmol/L−1 mmol/L

respectively. The detection limit is 6 nmol/L for rutin and 2 μmol/L for AA (S/N = 3)

which are lower than those of the reported electrochemical sensors.

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