Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers：Determination of Monomer Reactivity Ratios and Temperature Dependence

Qing-fei Zhang; Xiu-bo Jiang; Ai-hua He

doi:10.1007/s10118-014-1467-0

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Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers：Determination of Monomer Reactivity Ratios and Temperature Dependence

Updated：2021-06-21

- Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers：Determination of Monomer Reactivity Ratios and Temperature Dependence
- Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers: Determination of Monomer Reactivity Ratios and Temperature Dependence
- Chinese Journal of Polymer Science 2014年32卷第8期页码：1068-1076
- Affiliations：
  
  Key Laboratory of Rubber-Plastics (Ministry of Education)/Shandong Provincial, Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  **Ai-hua He (贺爱华), E-mail: aihuahe@iccas.ac.cn
- Funds：
  
  National Scientific Supporting Program from Ministry of Science and Technology of China(2011BAE26B05);Shandong Province Natural Science Fund for Distinguished Young Scholars(JQ201213);National Natural Science Foundation of China(21174074);Shandong Province Science and Technology Development Plan(2012GGA05042);Major Projects of Independent Innovation Achievements Transformation in Shandong Province(2013ZHZX1A0207)
- DOI：10.1007/s10118-014-1467-0
  中图分类号：
- 收稿：2013-12-05，
  
  修回：2014-01-07，
  
  录用：2014-01-13，
  
  纸质出版：2014-08
- Accepted：
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Qing-fei Zhang, Xiu-bo Jiang, Ai-hua He. Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers：Determination of Monomer Reactivity Ratios and Temperature Dependence[J]. Chinese Journal of Polymer Science, 2014,32(8):1068-1076.

Qing-fei Zhang, Xiu-bo Jiang, Ai-hua He. Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers: Determination of Monomer Reactivity Ratios and Temperature Dependence[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1068-1076.
Qing-fei Zhang, Xiu-bo Jiang, Ai-hua He. Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers：Determination of Monomer Reactivity Ratios and Temperature Dependence[J]. Chinese Journal of Polymer Science, 2014,32(8):1068-1076. DOI： 10.1007/s10118-014-1467-0.

Qing-fei Zhang, Xiu-bo Jiang, Ai-hua He. Synthesis and Characterization of trans-1,4-Butadiene/Isoprene Copolymers: Determination of Monomer Reactivity Ratios and Temperature Dependence[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1068-1076. DOI： 10.1007/s10118-014-1467-0.

摘要

Abstract

A series of

trans

-1

4-butadiene/isoprene copolymers were prepared using the catalyst system TiCl

/MgCl

-Al(

-Bu)

with bulk precipitation technology at different temperatures. Monomers reactivity ratios were calculated based on the Kelen-Tüdös (K-T) method and the Mao-Huglin (M-H) method. The influence of temperature on copolymer composition and polymerization rate was discussed in detail. The increase of reaction temperature brought the decrease of butadiene reactivity ratio

and supplied an effective adjustment on copolymers' composition distribution.

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