Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes

Tian Sun; Yu-feng Zhang; Chun-lin Chen; Xiang-zhuang Gong; Jian-qiang Meng

doi:10.1007/s10118-014-1462-5

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Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes

Updated：2021-06-21

- Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes
- Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes
- Chinese Journal of Polymer Science 2014年32卷第7期页码：880-891
- Affiliations：
  
  State Key Laboratory of Hollow Fiber Membrane Material and Membrane Process, Tianjin Polytechnic University, Tianjin 300387, China
- Author bio：
  
  **Yu-feng Zhang (张宇峰), E-mail: zyf9182@163.com
  Jian-qiang Meng (孟建强), E-mail: jianqiang.meng@hotmail.com
- Funds：
  
  National Natural Science Foundation of China(21274108);National High Technology Research and Development Program of China(2012AA03A602)
- DOI：10.1007/s10118-014-1462-5
  中图分类号：
- 收稿：2013-10-09，
  
  修回：2013-12-20，
  
  录用：2013-12-31，
  
  纸质出版：2014-07
- Accepted：
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Tian Sun, Yu-feng Zhang, Chun-lin Chen, 等. Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes[J]. Chinese Journal of Polymer Science, 2014,32(7):880-891.

Tian Sun, Yu-feng Zhang, Chun-lin Chen, et al. Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes[J]. Chinese Journal of Polymer Science, 2014, 32(7): 880-891. DOI: 10.1007/s10118-014-1462-5.
Tian Sun, Yu-feng Zhang, Chun-lin Chen, 等. Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes[J]. Chinese Journal of Polymer Science, 2014,32(7):880-891. DOI： 10.1007/s10118-014-1462-5.

Tian Sun, Yu-feng Zhang, Chun-lin Chen, et al. Synthesis of Membrane Adsorbers via Surface Initiated ATRP of 2-Dimethylaminoethyl Methacrylate from Microporous PVDF Membranes[J]. Chinese Journal of Polymer Science, 2014, 32(7): 880-891. DOI: 10.1007/s10118-014-1462-5. DOI：

摘要

Abstract

Surface-initiated atom transfer radical polymerization (SI-ATRP) was used to tether poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) onto microporous PVDF membranes in order to synthesize membrane adsorbers for protein adsorption. The alkaline treatment and bromine addition reaction were used to anchor ATRP initiators on membrane surface. Then PDMAEMA was grafted from the membrane surface

via

SI-ATRP. Fourier transform infrared spectroscopy (FTIR)

X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) revealed the chemical composition and surface topography of the PVDF-

-PDMAEMA membrane surfaces. These results showed that PDMAEMA was grafted from the membrane surface successfully and a grafting yield as high as 1500 μg/cm

was achieved. The effects of the grafting time and the density of initiators on the static and dynamic binding capacity of bovine serum albumin (BSA) were systematically investigated. Both the static and dynamic binding capacities increase with the bromination and polymerization time. However

the benefits of the initiator density on binding capacities are limited by the graft density of PDMAEMA chains.

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