Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose
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Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose
Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose
Chinese Journal of Polymer Science2014年32卷第4期 页码:439-448
Affiliations:
Chemicobiology and Functional Material Institute, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Author bio:
**Dong-ping Sun (孙东平), E-mail: sundpe301@163.com
Funds:
Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD);Jiangsu Provincial Department of Personnel;National High Technology Research and Development Program of China(2010AA0500293002)
Chun-tao Chen, Yang Huang, Chun-lin Zhu, 等. Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose[J]. Chinese Journal of Polymer Science, 2014,32(4):439-448.
Chun-tao Chen, Yang Huang, Chun-lin Zhu, et al. Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose[J]. Chinese Journal of Polymer Science, 2014, 32(4): 439-448.
Chun-tao Chen, Yang Huang, Chun-lin Zhu, 等. Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose[J]. Chinese Journal of Polymer Science, 2014,32(4):439-448.DOI: 10.1007/s10118-014-1419-8.
Chun-tao Chen, Yang Huang, Chun-lin Zhu, et al. Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose[J]. Chinese Journal of Polymer Science, 2014, 32(4): 439-448.DOI: 10.1007/s10118-014-1419-8.
Synthesis and Characterization of Hydroxypropyl Cellulose from Bacterial Cellulose
Bacterial cellulose produced by Acetobacter xylinum has been reacted with propyleneoxide to synthesize hydroxypropyl cellulose (HPC) under different reaction conditions while diluted by toluene. The effects of mass ratio of bacterial cellulose to propyleneoxide
dilutability of toluene
reaction temperature (
T
) and time (
t
) were investigated by series of experiments. The degree of substitution (DS)
hydroxypropyl content (
A
) and yield (
η
) were compared. The optimized product exhibited cold-water solubility and hot-water gelatinization in aqueous medium. Further study was carried out with FTIR
TGA
XRD
SEM and
13
C-NMR for characterization. The water/air contact angle measurement reveals that it is a good hydrophobic material with good mechanical properties.
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