A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS

Mohammad Ali; Karimi Zarchi; Ali Tarabsaz

doi:10.1007/s10118-013-1362-0

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A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS

PAPER | Updated：2023-01-03

- A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS
- A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS
- Chinese Journal of Polymer Science 2013年31卷第12期页码：1660-1669
- Affiliations：
  
  Department of Chemistry, College of Science, Yazd University, Yazd, Iran
- Author bio：
  
  *Karimi Zarchi, E-mail: makarimi@yazd.ac.ir
- Funds：
- DOI：10.1007/s10118-013-1362-0
  中图分类号：
- 收稿：2013-01-04，
  
  修回：2013-02-04，
  
  录用：2013-02-05，
  
  纸质出版：2013-12
- Accepted：
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Mohammad Ali, Karimi Zarchi, Ali Tarabsaz. A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS[J]. Chinese Journal of Polymer Science, 2013,31(12):1660-1669.

Mohammad Ali, Karimi Zarchi, Ali Tarabsaz. A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS[J]. Chinese Journal of Polymer Science, 2013, 31(12): 1660-1669.
Mohammad Ali, Karimi Zarchi, Ali Tarabsaz. A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS[J]. Chinese Journal of Polymer Science, 2013,31(12):1660-1669. DOI： 10.1007/s10118-013-1362-0.

Mohammad Ali, Karimi Zarchi, Ali Tarabsaz. A VERSATILE AND REGIOSELECTIVE SYNTHESIS OF VICINAL AZIDOALCOHOLS USING CROSS-LINKED POLY(4-VINYLPYRIDINE) SUPPORTED AZIDE ION UNDER SOLVENT-FREE CONDITIONS[J]. Chinese Journal of Polymer Science, 2013, 31(12): 1660-1669. DOI： 10.1007/s10118-013-1362-0.

摘要

Abstract

A new polymeric reagent

cross-linked poly(4-vinylpyridine) supported azide ion

-VP]N

was introduced as polymeric reagents for efficient and regioselective conversion of epoxides to azidohydrins in the presence of cross-linked poly(4-vinylpyridine) supported sulfuric acid

-VP]H

as a solid proton source and as catalyst under solvent-free conditions. The advantages of this polymeric reagent over some of those reported in the literature are easy work-up procedure and regeneration of the reagent.

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