INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-<italic style="font-style: italic">co</italic>-ACRYLONITRILE) BLENDS

De-zheng Pang; Min Zuo; Ji-shi Zhao; Qiang Zheng

doi:10.1007/s10118-013-1356-y

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INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS

PAPER | Updated：2023-01-03

- INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS
- INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS
- Chinese Journal of Polymer Science 2013年31卷第11期页码：1470-1483
- Affiliations：
  
  Key Laboratory of Macromolecule Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  **Min Zuo (左敏), E-mail: kezuomin@zju.edu.cn
  Qiang Zheng (郑强), E-mail: zhengqiang@zju.edu.cn
- Funds：
  
  National Natural Science Foundation of China(51003093);Zhejiang Provincial Innovative Research Team(2009R50004);Research Foundation of Education Bureau of Zhejiang Province(Y200908238)
- DOI：10.1007/s10118-013-1356-y
  中图分类号：
- 收稿：2013-04-15，
  
  修回：2013-05-28，
  
  录用：2013-06-03，
  
  纸质出版：2013-11
- Accepted：
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De-zheng Pang, Min Zuo, Ji-shi Zhao, 等. INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS[J]. Chinese Journal of Polymer Science, 2013,31(11):1470-1483. DOI: 10.1007/s10118-013-1356-y.

De-zheng Pang, Min Zuo, Ji-shi Zhao, et al. INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1470-1483. DOI: 10.1007/s10118-013-1356-y.
De-zheng Pang, Min Zuo, Ji-shi Zhao, 等. INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS[J]. Chinese Journal of Polymer Science, 2013,31(11):1470-1483. DOI: 10.1007/s10118-013-1356-y. DOI：

De-zheng Pang, Min Zuo, Ji-shi Zhao, et al. INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS[J]. Chinese Journal of Polymer Science, 2013, 31(11): 1470-1483. DOI: 10.1007/s10118-013-1356-y. DOI：

摘要

Abstract

The effect of clay on the morphology and phase-separation behavior of poly(methyl methacrylate)/poly(styreneco-acrylonitrile) (PMMA/SAN) blends and the variation of clay dispersion have been investigated. With the evolution of phase separation in PMMA/SAN

most of the clays are first located at the boundaries between PMMA and SAN

and then gradually move to the PMMA-rich domain

owing to the affinity of clay to PMMA. The introduction of clay causes the increase of binodal and spinodal temperatures of PMMA/SAN and enlarges their metastable region

indicating the phase stabilizing effect of clay on the matrix. But the influence of clay on the cloud points obviously depends on the composition of PMMA/SAN. The selective adsorption of PMMA on the clay results in the difference between the composition of surface layer and that of polymer matrix. Hence

the clay plays the role of an agent changing the conditions of phase structure formation.

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INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS

INFLUENCE OF CLAY ON THE MORPHOLOGY AND PHASE SEPARATION BEHAVIOR OF POLY(METHYL METHACRYLATE)/POLY(STYRENE-co-ACRYLONITRILE) BLENDS

DOI：10.1007/s10118-013-1356-y

摘要

Abstract

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