A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A4+B2+C2" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED

Wen-bo Wu; Shang-hui Ye; Li-jin Huang; Gui Yu; Yun-qi Liu; Jin-gui Qin; Zhen Li

doi:10.1007/s10118-013-1328-2

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A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED

PAPER | Updated：2023-01-03

- A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED
- A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED
- Chinese Journal of Polymer Science 2013年31卷第10期页码：1432-1442
- Affiliations：
  
  a.Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan 430072, China
  b.Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  **Zhen Li (李振), E-mail: lizhen@whu.edu.cn, lichemlab@163.com
  Yun-qi Liu (刘云圻), E-mail: liuyq@iccas.ac.cn
- Funds：
  
  NSFC(21161160556)
- DOI：10.1007/s10118-013-1328-2
  中图分类号：
- 收稿：2012-11-02，
  
  修回：2013-01-12，
  
  录用：2013-01-17，
  
  纸质出版：2013-10
- Accepted：
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Wen-bo Wu, Shang-hui Ye, Li-jin Huang, 等. A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED[J]. Chinese Journal of Polymer Science, 2013,31(10):1432-1442. DOI: 10.1007/s10118-013-1328-2.

Wen-bo Wu, Shang-hui Ye, Li-jin Huang, et al. A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED[J]. Chinese Journal of Polymer Science, 2013, 31(10): 1432-1442. DOI: 10.1007/s10118-013-1328-2.
Wen-bo Wu, Shang-hui Ye, Li-jin Huang, 等. A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED[J]. Chinese Journal of Polymer Science, 2013,31(10):1432-1442. DOI: 10.1007/s10118-013-1328-2. DOI：

Wen-bo Wu, Shang-hui Ye, Li-jin Huang, et al. A FUNCTIONAL CONJUGATED HYPERBRANCHED POLYMER DERIVED FROM TETRAPHENYLETHENE AND OXADIAZOLE MOIETIES: SYNTHESIS BY ONE-POT "A₄+B₂+C₂" POLYMERIZATION AND APPLICAION AS EXPLOSIVE CHEMOSENSOR AND PLED[J]. Chinese Journal of Polymer Science, 2013, 31(10): 1432-1442. DOI: 10.1007/s10118-013-1328-2. DOI：

摘要

Abstract

A new conjugated hyperbranched polymer (

-TFO) containing tetraphenylethylene (TPE) units

a famous aggregation-induced emission (AIE) active group

as the core

was synthesized successfully with modest yield via one-pot Suzuki polymerization reaction. Thanks to the introduction of TPE moieties

-TFO exhibited aggregation-enhanced emission (AEE) property

and could work as explosive chemosensor with high sensitivity. The polymeric light-emitting diode (PLED) device was fabricated to investigate its electroluminescent property

and

-TFO demonstrated a maximum luminance efficiency of 0.22 cd/A and a maximum brightness of 545 cd/m

at 15.9 V.

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