SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS

Ying-dong Xia; Ji-zhong Chen; Tong-fei Shi; Li-jia An

doi:10.1007/s10118-013-1322-8

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SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS

Special Issue: In Memory of Prof. Bingzheng Jiang | Updated：2023-01-03

- SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS
- SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS
- Chinese Journal of Polymer Science 2013年31卷第9期页码：1242-1249
- Affiliations：
  
  State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  **Ji-zhong Chen (陈继忠), E-mail: jzchen@ciac.jl.cn
- Funds：
  
  National Natural Science Foundation of China(20804047;20774096;20734003);Innovation Group(50921062);Special Funds for National Basic Research Program of China(2009CB930100;2010CB631100)
- DOI：10.1007/s10118-013-1322-8
  中图分类号：
- 收稿：2013-03-21，
  
  修回：2013-05-24，
  
  录用：2013-05-28，
  
  纸质出版：2013-09
- Accepted：
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Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, 等. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013,31(9):1242-1249.

Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, et al. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1242-1249.
Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, 等. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013,31(9):1242-1249. DOI： 10.1007/s10118-013-1322-8.

Ying-dong Xia, Ji-zhong Chen, Tong-fei Shi, et al. SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS[J]. Chinese Journal of Polymer Science, 2013, 31(9): 1242-1249. DOI： 10.1007/s10118-013-1322-8.

摘要

Abstract

The self-assembly of the linear rod-coil multiblock copolymers is studied by applying self-consistent-field lattice techniques in a three-dimensional (3D) space. Compared to the copolymer with one rod

the copolymer with more rods (

rod

≥ 2) exhibits rich order-order phase transitions with increasing temperature

where the ordered morphology changes from strips to perforated lamellae and finally to lamellae. In addition

taking the copolymer with

rod

= 2 as a representative

we further study the effects of the volume fractions of the rods

the spacer coils and the end coils on the phase behaviors respectively

by which the detailed self-assembled mechanism of the linear rod-coil multiblock copolymers is revealed. Our results are expected to provide guidance for the design of the rod-coil materials.

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