SYNTHESIS OF NATURAL RUBBER-<italic style="font-style: italic">g</italic>-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES

Zhi-xian Dong; Ming-xian Liu; De-min Jia; Yan-hao Zhou

doi:10.1007/s10118-013-1310-z

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SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES

PAPER | Updated：2023-01-03

- SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES
- SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES
- Chinese Journal of Polymer Science 2013年31卷第8期页码：1127-1138
- Affiliations：
  
  a.College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China
  b.School of Materials and Energy, Guangdong University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, China
- Author bio：
  
  Zhi-xian Dong (董智贤), E-mail: zxdong@gdut.edu.cn
  **De-min Jia (贾德民), E-mail: psdmjia@scut.edu.cn
- Funds：
  
  Joint Funds of the National Natural Science Foundation of China and Guangdong Province(U1134005)
- DOI：10.1007/s10118-013-1310-z
  中图分类号：
- 收稿：2012-09-27，
  
  修回：2012-11-21，
  
  录用：2012-11-23，
  
  纸质出版：2013-08
- Accepted：
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Zhi-xian Dong, Ming-xian Liu, De-min Jia, 等. SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES[J]. Chinese Journal of Polymer Science, 2013,31(8):1127-1138. DOI: 10.1007/s10118-013-1310-z.

Zhi-xian Dong, Ming-xian Liu, De-min Jia, et al. SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES[J]. Chinese Journal of Polymer Science, 2013, 31(8): 1127-1138. DOI: 10.1007/s10118-013-1310-z.
Zhi-xian Dong, Ming-xian Liu, De-min Jia, 等. SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES[J]. Chinese Journal of Polymer Science, 2013,31(8):1127-1138. DOI: 10.1007/s10118-013-1310-z. DOI：

Zhi-xian Dong, Ming-xian Liu, De-min Jia, et al. SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES[J]. Chinese Journal of Polymer Science, 2013, 31(8): 1127-1138. DOI: 10.1007/s10118-013-1310-z. DOI：

摘要

Abstract

Natural rubber grafted maleic anhydride (NR-

-MAH) was synthesized by mixing maleic anhydride (MAH) and natural rubber (NR) in solid state in a torque rheometer using dicumyl peroxide (DCP) as initiator. Then the self-prepared NR-

-MAH was used as a compatibilizer in the natural rubber/short nylon fiber composites. Both the functionalization of NR with MAH and the reaction between the modified rubber and the nylon fiber were confirmed by Fourier transform infrared spectroscopy (FTIR). Composites with different nylon short fiber loadings (0

15 and 20 phr) were compounded on a two-roll mill

and the effects of the NR-

-MAH on the tensile and thermal properties

fiber-rubber interaction

as well as the morphology of the natural rubber/short nylon fiber composites were investigated. At equal fiber loading

the NR-

-MAH compatibilized NR/short nylon fiber composites showed improved tensile properties

especially the tensile modulus at 100% strain which was about 1.5 times that of the corresponding un-compatibilized ones. The equilibrium swelling tests proved that the incorporation of NR-

-MAH increased the interaction between the nylon fibers and the NR matrix. The crosslink density measured with NMR techniques showed that the NR-

-MAH compatiblized composites had lower total crosslink density. The glass transition temperatures of the compatibilized composites were about 1 K higher than that of the corresponding un-compabilized ones. Morphology analysis of the NR/short nylon fiber composites confirmed NR-

-MAH improved interfacial bonding between the NR matrix and the nylon fibers. All these results signified that the NR-

-MAH could act as a good compatilizer of NR/short nylon fiber composites and had a potential for wide use considering its easy to be prepared and compounded with the composites.

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SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES

SYNTHESIS OF NATURAL RUBBER-g-MALEIC ANHYDRIDE AND ITS USE AS A COMPATIBILIZER IN NATURAL RUBBER/SHORT NYLON FIBER COMPOSITES

DOI：10.1007/s10118-013-1310-z

摘要

Abstract

关键词

Keywords

references