PURIFIED POLAR POLYFLUORENE FOR LIGHT-EMITTING DIODES AND LIGHT-EMITTING ELECTROCHEMICAL CELLS
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PURIFIED POLAR POLYFLUORENE FOR LIGHT-EMITTING DIODES AND LIGHT-EMITTING ELECTROCHEMICAL CELLS
PURIFIED POLAR POLYFLUORENE FOR LIGHT-EMITTING DIODES AND LIGHT-EMITTING ELECTROCHEMICAL CELLS
Chinese Journal of Polymer Science2012年30卷第4期 页码:503-510
Affiliations:
a.Department of Materials Science and Engineering, University of California at Los Angeles, Los Angeles, California 90095, USA
b.Institute of Material Science and Engineering, Ocean University of China, Qingdao 266100, China
c.Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
d.School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Author bio:
**Ming-liang Sun (孙明亮), E-mail: mlsun@ouc.edu.cn
Funds:
National Natural Science Foundation of China(50903078);Specialized Research Fund for the Doctoral Program of Higher Education (New Teachers)(20090132120017);Promotive research fund for excellent young and middle-aged scientisits of Shandong Province(BS2009CL036);Fundamental Research Funds for the Central Universities(201113045)
Conjugated ployfluorene with 2-(2-(2-methoxyethoxy)ethoxy)ethyl groups (EO-PF) is prepared by the palladiumcatalyzed Suzuki coupling reaction. The polymer is purified carefully by a simple chemical procedure. The inductively coupled plasma (ICP) test shows palladium-catalyst in the polymer can be removed by this procedure. The thermal properties
electrochemical properties
UV-Vis absorption properties
photoluminescence properties and electroluminescent properties of the polymer without (EO-PF1) or with purification (EO-PF2) are studied. EO-PF2 shows better PL CIE coordinates in THF solutions as blue light-emitting materials and better photoluminescence stability in thin solid films. Polymer light emitting diodes and electrochemical cells based on EO-PF2 exhibit somewhat improved optoelectronic performance than control devices of EO-PF1.
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相关作者
Li-Wen Hu
Liang Li
Yong Yang
Ting Guo
Yu-Hao Zhang
Wei Yang
Yong Cao
Lv Wei
相关机构
College of Chemistry and Chemical Engineering, College of Materials Science and Engineering, Fujian Normal University, Fujian Key Laboratory of Polymer Materials