CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION

Xiao-ying Lu; Jian-jun Yi; Shang-tao Chen; Feng-hua Zu; Rong-bo Li

doi:10.1007/s10118-012-1097-3

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CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION

Paper | Updated：2023-01-03

- CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION
- CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION
- Chinese Journal of Polymer Science 2012年30卷第1期页码：122-129
- Affiliations：
  
  Petrochina Petrochemical Research Institute, Beijing 100195, China
- Author bio：
  
  **Jian-jun Yi (义建军), E-mail: yijianjun@petrochina.com.cn
- Funds：
  
  Science and Technology Project of PetroChina Refining & Chemicals Company(0904A07-19);Petrochemical Research Institute Innovation Project(09-YK-05-20)
- DOI：10.1007/s10118-012-1097-3
  中图分类号：
- 收稿：2011-02-15，
  
  修回：2011-04-07，
  
  录用：2011-04-18，
  
  纸质出版：2012-01
- Accepted：
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Xiao-ying Lu, Jian-jun Yi, Shang-tao Chen, 等. CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION[J]. Chinese Journal of Polymer Science, 2012,30(1):122-129.

Xiao-ying Lu, Jian-jun Yi, Shang-tao Chen, et al. CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION[J]. Chinese Journal of Polymer Science, 2012, 30(1): 122-129.
Xiao-ying Lu, Jian-jun Yi, Shang-tao Chen, 等. CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION[J]. Chinese Journal of Polymer Science, 2012,30(1):122-129. DOI： 10.1007/s10118-012-1097-3.

Xiao-ying Lu, Jian-jun Yi, Shang-tao Chen, et al. CHARACTERIZATION OF IMPACT POLYPROPYLENE COPOLYMERS BY SOLVENT FRACTIONATION[J]. Chinese Journal of Polymer Science, 2012, 30(1): 122-129. DOI： 10.1007/s10118-012-1097-3.

摘要

Abstract

The compositional heterogeneity of two impact polypropylene copolymers (IPCs) was studied by a combinatory investigation of temperature rising elution fractionation (TREF) and solvent fractionation. The chain structures and composition of fractions obtained from solvent fractionation were examined in detail. The TREF results shows that there are much more E-P segmented copolymer and more uniform distribution of ethylene sequence in IPC-1

which is responsible for its better comprehensive mechanical performance. The fractions from hexane and heptane are ethylene-propylene rubber phase and E-P block copolymers respectively. The result of solvent fractionation method also shows that custom hexane or heptane extractions can not extract the E-P copolymer completely.

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