MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT

Ai-hua Chai; Lin-xi Zhang

doi:10.1007/s10118-011-1072-4

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MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT

Updated：2021-06-21

- MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT
- MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT
- Chinese Journal of Polymer Science 2011年29卷第6期页码：684-691
- Affiliations：
  
  a.Department of Physics, Zhejiang University, Hangzhou 310027, China
  b.Department of Physics, Wenzhou University, Wenzhou 325027, China
  c.College of Mathematics, Physics and Information Engineering, Jiaxing University, Jiaxing 314000, China
- Author bio：
  
  **Lin-xi Zhang (章林溪), E-mail: lxzhang@zju.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China(20774066;20974081;20934004);Ph. D. Programs Foundation of Ministry of Education of China(20090101110002);Natural Science Foundation of Zhejiang Province(Y4080098)
- DOI：10.1007/s10118-011-1072-4
  中图分类号：
- 收稿：2010-11-15，
  
  修回：2011-01-10，
  
  录用：2011-01-25，
  
  纸质出版：2011
- Accepted：
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Ai-hua Chai, Lin-xi Zhang. MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT[J]. Chinese Journal of Polymer Science, 2011,29(6):684-691.

Ai-hua Chai, Lin-xi Zhang. MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT[J]. Chinese Journal of Polymer Science, 2011, 29(6): 684-691.
Ai-hua Chai, Lin-xi Zhang. MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT[J]. Chinese Journal of Polymer Science, 2011,29(6):684-691. DOI： 10.1007/s10118-011-1072-4.

Ai-hua Chai, Lin-xi Zhang. MICRODOMAIN MORPHOLOGY OF CYLINDER-FORMING DIBLOCK COPOLYMERS UNDER SPHERICAL SHELL CONFINEMENT[J]. Chinese Journal of Polymer Science, 2011, 29(6): 684-691. DOI： 10.1007/s10118-011-1072-4.

摘要

Abstract

The topic of self-assembly of cylinder-forming diblock copolymers (DBCPs) under spherical shell confinement in different surface fields is explored using real-space self-consistent field theory calculations (SCFT). Using this approach we observed various microstructures of cylinder-forming DBCPs at different confinement dimensions and surface fields. From detailed searching for the microdomain morphologies

an obvious conclusion is that the interactions between the confinement surface and the polymers have a great effect on the self-assembly. Most of the microstructures are unique and not reported in bulk or under planar and cylindrical confinements.

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