EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS b-FORM NUCLEATING AGENT

Mu Dong; Ming-yin Jia; Zhao-xia Guo; Jian Yu

doi:10.1007/s10118-011-1031-0

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EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS b-FORM NUCLEATING AGENT

Paper | Updated：2021-06-21

- EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS b-FORM NUCLEATING AGENT
- EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS β-FORM NUCLEATING AGENT
- Chinese Journal of Polymer Science 2011年29卷第3期页码：308-317
- Affiliations：
  
  Institute of Polymer Science and Engineering, Department of Chemical Engineering, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  *Jian Yu (于建), E-mail: yujian03@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-011-1031-0
  中图分类号：
- 收稿：2010-03-18，
  
  修回：2010-07-07，
  
  录用：2010-07-09，
  
  纸质出版：2011
- Accepted：
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Mu Dong, Ming-yin Jia, Zhao-xia Guo, 等. EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS b-FORM NUCLEATING AGENT[J]. Chinese Journal of Polymer Science, 2011,29(3):308-317.

Mu Dong, Ming-yin Jia, Zhao-xia Guo, et al. EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS β-FORM NUCLEATING AGENT[J]. Chinese Journal of Polymer Science, 2011, 29(3): 308-317. DOI: 10.1007/s10118-011-1031-0.
Mu Dong, Ming-yin Jia, Zhao-xia Guo, 等. EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS b-FORM NUCLEATING AGENT[J]. Chinese Journal of Polymer Science, 2011,29(3):308-317. DOI： 10.1007/s10118-011-1031-0.

Mu Dong, Ming-yin Jia, Zhao-xia Guo, et al. EFFECT OF FINAL HEATING TEMPERATURE ON CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE NUCLEATED WITH AN ARYL AMIDE DERIVATIVE AS β-FORM NUCLEATING AGENT[J]. Chinese Journal of Polymer Science, 2011, 29(3): 308-317. DOI: 10.1007/s10118-011-1031-0. DOI：

摘要

Abstract

An aryl dicarboxylic acid amide compound TMB-5 is an efficient

-form nucleating agent for isotactic polypropylene (

PP). Because of the solubility of TMB-5

superstructure and morphology of

PP crystals changed with melting conditions. Effects of final heating temperature (

) on heterogeneous nucleation of

PP/TMB-5 were investigated. It was discovered that the crystallization temperature increased with decreasing

value. The optical microscopic images indicated that when TMB-5 partially dissolved in

PP melt

the remaining (non-dissolved) TMB-5 facilitated the recrystallization of dissolved nucleating agent from the melt

which promoted crystallization. Complete solubility of nucleating agent caused the decreasing efficiency. TMB-5 recrystallized in the form of tiny needles

whose aggregates induced dendritic

PP crystals.

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