ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE

Rui-rui Yue a; Jing-kun Xu a; Bao-yang Lu a; Cong-cong Liu a; Zhao-jin Zhu a; Zhuo Zhang b

doi:10.1007/s10118-010-9141-7

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ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE

Papers | Updated：2021-06-21

- ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE
- ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE
- 高分子科学（英文版） 2010年28卷第5期页码：771-780
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- DOI：10.1007/s10118-010-9141-7
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- 纸质出版：2010-09-20
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Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, 等. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 高分子科学（英文版）, 2010,28(5):771-780.

Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, et al. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 2010, 28(5): 771-780.
Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, 等. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 高分子科学（英文版）, 2010,28(5):771-780. DOI： 10.1007/s10118-010-9141-7.

Rui-rui Yue a, Jing-kun Xu a, Bao-yang Lu a, et al. ELECTROSYNTHESES AND CHARACTERIZATION OF A FLUORESCENT CONDUCTING COPOLYMER OF BENZANTHRONE AND THIOPHENE[J]. 2010, 28(5): 771-780. DOI： 10.1007/s10118-010-9141-7.

摘要

Poly(benzanthrone-co-thiophene)

a new conducting copolymer

was successfully prepared by direct anodic oxidation of benzanthrone and thiophene (Th) in a binary solvent system containing boron trifluoride diethyl etherate (BFEE) and acetonitrile (ACN). The as-formed copolymer film electrodeposited with monomer feed ratio of benzanthrone/Th = 1:1 at the applied potential of 1.3 V versus Ag/AgCl exhibited the advantages of both polybenzanthrone and polythiophene

such as active electrochemical behavior

excellent thermal stability

relatively high electrical conductivity and mechanical properties. UV-Vis spectroscopy

1H-NMR and SEM were used to characterize and investigate the structures and morphologies of the copolymers. Fluorescence spectroscopy studies revealed that the obtained copolymer films show strong emission at about 525 nm. Moreover

the emitting properties of the copolymers could be tuned by changing some parameters during the electropolymerization process

such as monomer feed ratio.

Abstract

Poly(benzanthrone-co-thiophene)

a new conducting copolymer

such as active electrochemical behavior

excellent thermal stability

relatively high electrical conductivity and mechanical properties. UV-Vis spectroscopy

the emitting properties of the copolymers could be tuned by changing some parameters during the electropolymerization process

such as monomer feed ratio.

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