SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS

Abdol-reza Hajipour a; Sakineh Habibi b; Arnold E. Ruoho a

doi:10.1007/s10118-010-9125-7

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SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS

Papers | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS
- SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS
- 高分子科学（英文版） 2010年28卷第5期页码：731-743
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- DOI：10.1007/s10118-010-9125-7
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- 纸质出版：2010-09-20
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Abdol-reza Hajipour a, Sakineh Habibi b, Arnold E. Ruoho a. SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS[J]. 高分子科学（英文版）, 2010,28(5):731-743.

Abdol-reza Hajipour a, b, Sakineh Habibi b. SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS[J]. 2010, 28(5): 731-743.
Abdol-reza Hajipour a, Sakineh Habibi b, Arnold E. Ruoho a. SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS[J]. 高分子科学（英文版）, 2010,28(5):731-743. DOI： 10.1007/s10118-010-9125-7.

Abdol-reza Hajipour a, b, Sakineh Habibi b. SYNTHESIS AND CHARACTERIZATION OF NOVEL OPTICALLY ACTIVE POLY(AMIDE-IMIDE)S AND POLY(ESTER-IMIDE)S CONTAINING CALIX[4]ARENE AND AMINO ACID UNITS WITH BINDING ABILITY TOWARDS ALKALI METAL AND TOXIC HEAVY METAL CATIONS[J]. 2010, 28(5): 731-743. DOI： 10.1007/s10118-010-9125-7.

摘要

A novel calix[4]arene derivative 2 with amino functional groups at the lower rim was first prepared via introduction of nitro functional groups and amination of the dinitro derivative of calix[4]arene. The optically active monomers were synthesized by dehydration of L-leucine (and L-isoleucine) and 3

4'-benzophenonetetracarboxylic-3

4'-dianhydride (3) followed by reaction with thionyl chloride to form 5a and 5b. Two methods

polymerization under microwave irradiation and solution polymerization in CH2Cl2/TEA

were then employed to carry out the condensation polymerization of 2 with the optically active monomers 5a and 5b

respectively. The polymerization conditions affected the kind of resulting polymers

poly(amide-imide)s (PAIs) 6a and 6b and poly(ester-imide)s (PEIs) 6a' and 6b' were obtained selectively in good yields and moderate inherent viscosities. Sorption-extraction experiments were carried out using cram picrate extraction method and verified good binding ability of the resulting calixarene-based polymers towards silver

alkali metal and toxic heavy metal cations. Also thermogravimetric analysis indicated that the resulting PAIs and PEIs were thermally stable.

Abstract

4'-benzophenonetetracarboxylic-3

4'-dianhydride (3) followed by reaction with thionyl chloride to form 5a and 5b. Two methods

polymerization under microwave irradiation and solution polymerization in CH2Cl2/TEA

were then employed to carry out the condensation polymerization of 2 with the optically active monomers 5a and 5b

respectively. The polymerization conditions affected the kind of resulting polymers

alkali metal and toxic heavy metal cations. Also thermogravimetric analysis indicated that the resulting PAIs and PEIs were thermally stable.

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