NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS

Ying-ying Pan a; Xi-fei Yu a; Tong-fei Shi a; Li-jia An a

doi:10.1007/s10118-010-9025-x

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NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS

Papers | Updated：2021-06-21

- NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS
- NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS
- 高分子科学（英文版） 2010年28卷第3期页码：347-355
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- DOI：10.1007/s10118-010-9025-x
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- 纸质出版：2010-05-20
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Ying-ying Pan a, Xi-fei Yu a, Tong-fei Shi a, 等. NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS[J]. 高分子科学（英文版）, 2010,28(3):347-355.

Ying-ying Pan a, b, Xi-fei Yu a, et al. NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS[J]. 2010, 28(3): 347-355.
Ying-ying Pan a, Xi-fei Yu a, Tong-fei Shi a, 等. NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS[J]. 高分子科学（英文版）, 2010,28(3):347-355. DOI： 10.1007/s10118-010-9025-x.

Ying-ying Pan a, b, Xi-fei Yu a, et al. NUCLEATION AND CRYSTALLIZATION OF H-SHAPED (PS)2PEG(PS)2 BLOCK COPOLYMERS[J]. 2010, 28(3): 347-355. DOI： 10.1007/s10118-010-9025-x.

摘要

A series of H-shaped (PS)2PEG(PS)2 block copolymers with different PS chain lengths were prepared. The influence of different confinements active on the crystallization and self-nucleation (SN) behavior of the PEG blocks was investigated by differential scanning calorimetry (DSC). When the content of the crystalline block was high

a classical SN behavior was obtained. The block copolymer with PEG content of 49% (by weight) showed a classical SN behavior with a narrow self-nucleation domain and had bimodal crystallization exotherms. When the PEG dispersed as separated microdomains in the block copolymer

the self-nucleation domain disappeared and only annealing was observed.

Abstract

the self-nucleation domain disappeared and only annealing was observed.

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