SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES

Ibrahim Erol; Cemal Cifci

doi:10.1007/s10118-010-1005-7

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SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES

Paper | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES
- SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES
- Chinese Journal of Polymer Science 2011年29卷第1期页码：101-110
- Affiliations：
  
  Department of Chemistry, Faculty of Arts and Science, University of Afyon Kocatepe, Afyonkarahisar, Turkey
- Author bio：
  
  *Ibrahim Erol, E-mail: iberol@hotmail.com; ierol@aku.edu.tr
- Funds：
- DOI：10.1007/s10118-010-1005-7
  中图分类号：
- 收稿：2009-12-30，
  
  修回：2010-02-08，
  
  录用：2010-03-01，
  
  纸质出版：2011
- Accepted：
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Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011,29(1):101-110.

Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011, 29(1): 101-110.
Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011,29(1):101-110. DOI： 10.1007/s10118-010-1005-7.

Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, 2011, 29(1): 101-110. DOI： 10.1007/s10118-010-1005-7.

摘要

Abstract

A new type of methacrylate monomer

2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate (BOEMA) was synthesized. The radical homopolymerization of BOEMA was performed at 65℃ in a 1

4-dioxane solution with benzoyl peroxide as an initiator. The oxime and thiosemicarbazone derivatives of poly[2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate] poly(BOEMA) were prepared with hydroxylamine hydrochloride

and thiosemicarbazone hydrochloride

respectively. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(BOEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers was compared. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa and Kissinger methods.

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