M. Ghaemy, M. Bazzar, H. Mighani. EFFECT OF NANOSILICA ON THE KINETICS OF CURE REACTION AND THERMAL DEGRADATION OF EPOXY RESIN[J]. Chinese Journal of Polymer Science, 2011,29(2):141-148.
M. Ghaemy, M. Bazzar, H. Mighani. EFFECT OF NANOSILICA ON THE KINETICS OF CURE REACTION AND THERMAL DEGRADATION OF EPOXY RESIN[J]. Chinese Journal of Polymer Science, 2011, 29(2): 141-148.
M. Ghaemy, M. Bazzar, H. Mighani. EFFECT OF NANOSILICA ON THE KINETICS OF CURE REACTION AND THERMAL DEGRADATION OF EPOXY RESIN[J]. Chinese Journal of Polymer Science, 2011,29(2):141-148.DOI: 10.1007/s10118-010-1003-9.
M. Ghaemy, M. Bazzar, H. Mighani. EFFECT OF NANOSILICA ON THE KINETICS OF CURE REACTION AND THERMAL DEGRADATION OF EPOXY RESIN[J]. Chinese Journal of Polymer Science, 2011, 29(2): 141-148.DOI: 10.1007/s10118-010-1003-9.
EFFECT OF NANOSILICA ON THE KINETICS OF CURE REACTION AND THERMAL DEGRADATION OF EPOXY RESIN
Nanocomposites from nanoscale silica particles (NS)
diglycidylether of bisphenol-A based epoxy (DGEBA)
and 3
5-diamino-
N
-(4-(quinolin-8-yloxy) phenyl) benzamide (DQPB) as curing agent were obtained from direct blending of these materials. The effect of nanosilica (NS) particles as catalyst on the cure reaction of DGEBA/DQPB system was studied by using non-isothermal DSC technique. The activation energy (
E
a
) was obtained by using Kissinger and Ozawa equations. The
E
a
value of curing of DGEBA/DQPB/10% NS system showed a decrease of about 10 kJ/mol indicating the catalytic effect of NS particles on the cure reaction. The
E
a
values of thermal degradation of the cured samples of both systems were 148 kJ/mol and 160 kJ/mol
respectively. The addition of 10% of NS to the curing mixture did not have much effect on the initial decomposition temperature (
T
i
) but increased the char residues from 20% to 28% at 650℃.
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