Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends

Kang-Jing Zhang; Zhao-Bin Qiu

doi:10.1007/S10118-019-2269-1

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Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends

ARTICLE | Updated：2021-02-18

- Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends
- Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends
- Chinese Journal of Polymer Science 2019年37卷第11期页码：1169-1175
- Affiliations：
  
  1.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  qiuzb@mail.buct.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51573016).
- DOI：10.1007/S10118-019-2269-1
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Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019,37(11):1169-1175.

Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019,37(11):1169-1175.
Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019,37(11):1169-1175. DOI： 10.1007/S10118-019-2269-1.

Kang-Jing Zhang, Zhao-Bin Qiu. Miscibility and Crystallization Behavior of Novel Branched Poly(ethylene succinate)/Poly(vinyl phenol) Blends[J]. Chinese Journal of Polymer Science, 2019,37(11):1169-1175. DOI： 10.1007/S10118-019-2269-1.

摘要

Abstract

The blends of novel branched poly(ethylene succinate) (b-PES) and poly(vinyl phenol) (PVPh) were prepared ,via, a solution and casting method. The miscibility, melting behavior, spherulitic morphology and growth, and crystal structure of b-PES/PVPh blends were investigated in detail. PVPh was miscible with b-PES over the whole compositions as evidenced by the single composition dependent glass transition temperature. Double melting behavior occurred in neat b-PES and b-PES/PVPh 85/15 blend after isothermal melt crystallization, which may be explained by the melting, recrystallization, and remelting mechanism. In addition, the depression of equilibrium melting point of an 85/15 blend was also found, confirming again the miscibility between the two components. The addition of PVPh caused the decrease of nucleation density and crystal growth rates of b-PES spherulites in the blend. The crystal structure of b-PES was unchanged before and after blending; moreover, the crystallinity of b-PES decreased slightly in the blend.

关键词

Keywords

Polymer blendsMiscibilityCrystallization behavior

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