SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Jacky W.Y.Lam; Kevin K.L.Cheuk

Your Location：

Home >

Browse articles >

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Rapid Communication | Updated：2021-06-21

- SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S
- SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S
- 高分子科学（英文版） 2007年第2期页码：119-122
- Affiliations：
  
  1.   Department of Chemistry The Hong Kong University of Science & Technology
  2.   Clear Water Bay
  3.   Kowloon
  4.   China
- Author bio：
- Funds：
  
  This work was partially supported by the Research Grants Council of Hong Kong（Nos. 602706, HKU2/05C, 603505,603304, and 664903）.()
- DOI：
  中图分类号： TQ317
- 纸质出版：2007
- Accepted：
Scan QR Code
[1]Jacky W.Y.Lam,Kevin K.L.Cheuk.SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY(PHENYLACETYLENE)S[J].Chinese Journal of Polymer Science,2007(02):119-122.

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007, (2): 119-122.
[1]Jacky W.Y.Lam,Kevin K.L.Cheuk.SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY(PHENYLACETYLENE)S[J].Chinese Journal of Polymer Science,2007(02):119-122. DOI：

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007, (2): 119-122. DOI：

摘要

<正>Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

Abstract

Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport