SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Jacky W.Y.Lam; Kevin K.L.Cheuk

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SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S

Rapid Communication | Updated：2021-06-21

- SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S
- SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S
- 高分子科学（英文版） 2007年第2期页码：119-122
- Affiliations：
  
  1.   Department of Chemistry The Hong Kong University of Science & Technology
  2.   Clear Water Bay
  3.   Kowloon
  4.   China
- Author bio：
- Funds：
  
  This work was partially supported by the Research Grants Council of Hong Kong（Nos. 602706, HKU2/05C, 603505,603304, and 664903）.()
- DOI：
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Jacky W.Y.Lam, Kevin K.L.Cheuk. SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 高分子科学（英文版）, 2007,(2):119-122.

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007,(2):119-122.
Jacky W.Y.Lam, Kevin K.L.Cheuk. SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 高分子科学（英文版）, 2007,(2):119-122. DOI：

SYNTHESIS,HELICITY,AND BIOLOGICAL PROPERTIES OF MONOSACCHARIDE-CONTAININGPOLY（PHENYLACETYLENE）S[J]. 2007,(2):119-122. DOI：

摘要

<正>Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

Abstract

Poly（phenylacetylene）s bearing monosaccharide pendant groups are synthesized in high yields by [Rh（nbd）Cl]2 catalyst. The polymers have high molecular weights and give satisfactory spectroscopic data corresponding to their molecular structures. They are thermally quite stable （≥300℃） and show strong circular dichroism signals in the visible spectral region owing to the helicity of the polyene backbone. The monosaccharide-containing polyacetylenes are cytophilic and can stimulate the growth of living cells.

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