CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES

Han Peng Xiu-wen Zheng~a Jacky W.Y.Lam~b Ben-zhong Tang~() ~aInstitute of Material Science and Engineering; South China University of Technology; Guangzhou 510640; China ~bDepartment of Chemistry; Hong Kong University of Science & Technology; Clear Water Bay; Kowloon; Hong Kong; China

Your Location：

Home >

Browse articles >

CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES

Updated：2021-06-21

- CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES
- CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES
- 高分子科学（英文版） 2007年第6期页码：641-649
- Affiliations：
- Author bio：
- Funds：
  
  This project was financially supported by National Natural Science Foundation of China（No.50473034）.()
- DOI：
  中图分类号： O631
- 纸质出版：2007
- Accepted：
Scan QR Code
[1].CARBAZOLE-CONTAINING HYPERBRANCHED POLY(ARYLENEETHYNYLENE)S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES[J].Chinese Journal of Polymer Science,2007(06):641-649.

Han Peng Xiu-wen Zheng~a Jacky W.Y.Lam~b Ben-zhong Tang~() ~aInstitute of Material Science and Engineering, South China University of Technology, Guangzhou 510640, et al. CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES[J]. 2007, (6): 641-649.
[1].CARBAZOLE-CONTAINING HYPERBRANCHED POLY(ARYLENEETHYNYLENE)S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES[J].Chinese Journal of Polymer Science,2007(06):641-649. DOI：

Han Peng Xiu-wen Zheng~a Jacky W.Y.Lam~b Ben-zhong Tang~() ~aInstitute of Material Science and Engineering, South China University of Technology, Guangzhou 510640, et al. CARBAZOLE-CONTAINING HYPERBRANCHED POLY（ARYLENEETHYNYLENE）S:SYNTHESIS,CHARACTERIZATION,ANDPROPERTIES[J]. 2007, (6): 641-649. DOI：

摘要

正

New hyperbranched poly（aryleneethynylene）s containing carbazole moieties are synthesized in high yields（up to 87%）by polycyclotrimerization of 3

6-bis（4-ethynylphenyl）-9-octylcarbazole and its copolymerization with 1-octyne catalyzed by CpCo（CO）

in THF.The structures and properties of the polymers are characterized and evaluated by IR

NMR

TGA

photoluminescence

and cyclic voltammetry analyses.All the polymers are soluble in common organic solvents and show outstanding thermal stability（≥430℃）.They graphitize in high yields（up to 79%）when pyrolyzed at 800℃. Upon photoexcitation

the polymers emit a strong deep blue light of ca.400 nm with quantum yields larger than 60%.

Abstract

New hyperbranched poly（aryleneethynylene）s containing carbazole moieties are synthesized in high yields（up to 87%）by polycyclotrimerization of 3

6-bis（4-ethynylphenyl）-9-octylcarbazole and its copolymerization with 1-octyne catalyzed by CpCo（CO）

in THF.The structures and properties of the polymers are characterized and evaluated by IR

NMR

TGA

photoluminescence

the polymers emit a strong deep blue light of ca.400 nm with quantum yields larger than 60%.

关键词

Keywords

references

浏览量

167

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair