EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS
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EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS
EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS
高分子科学(英文版)2007年第3期 页码:235-244
Affiliations:
1. Department of Environment Engineering College of Urban Construction and Safety & Environmental Engineering
2. Nanjing University of Technology
3. Nanjing 210009
4. China Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources and Environmental Protection
5. Yancheng 224002
Author bio:
Funds:
This work was supported by the Opening Foundation of Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources and Environmental Protection of China (No. JLCBE05006).()
DOI:
中图分类号:TQ028.15
纸质出版:2007
Accepted:
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[1]王海玲.EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS[J].Chinese Journal of Polymer Science,2007(03):235-244.
EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS[J]. 2007, (3): 235-244.
[1]王海玲.EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS[J].Chinese Journal of Polymer Science,2007(03):235-244.DOI:
EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS[J]. 2007, (3): 235-244.DOI:
EFFECT OF pH ON THE ADSORPTION OFp-AMINOBENZOIC ACID ON POLYSTYRENE-BASED ADSORBENTS
<正>In the present study the adsorptive properties of p-aminobenzoic acid with hypercrosslinked and multi-functional polymeric adsorbents at different solution pHs were systematically investigated in accordance with the particular physicochemical characteristics of the aromatic amphoteric compound involving both Lewis acid and Lewis base functional groups. It was found that the equilibrium adsorption data of the three polymeric adsorbents fitted well in the Langmuir and Freundlich isotherm equations. Studies at various pH levels indicate that the capacity of the adsorbents for adsorption of the ionic forms of adsorbate is less than that for the corresponding neutral species. At pH 3.78
the adsorption capacities of the three adsorbents are the highest. Whereas the adsorption property of multi-functional polymeric adsorbent NJ-99 is the largest
which may be attributed to the strong hydrogen-bonding interaction between the amino groups on the resin and the carboxyl group of p-aminobenzoic acid. The trend of the adsorption capacities of the three adsorbents towards p-aminobenzoic acid with the solution pH is in accord with the dissociation curve of the neutral molecular p-aminobenzoic acid. The adsorption forces includeπ-πinteraction
hydrogen-bonding interaction and electrostatic attraction or repulsion when there exist the molecular and ionic adsorbing species at different pHs in aqueous solution.
Abstract
In the present study the adsorptive properties of p-aminobenzoic acid with hypercrosslinked and multi-functional polymeric adsorbents at different solution pHs were systematically investigated in accordance with the particular physicochemical characteristics of the aromatic amphoteric compound involving both Lewis acid and Lewis base functional groups. It was found that the equilibrium adsorption data of the three polymeric adsorbents fitted well in the Langmuir and Freundlich isotherm equations. Studies at various pH levels indicate that the capacity of the adsorbents for adsorption of the ionic forms of adsorbate is less than that for the corresponding neutral species. At pH 3.78
the adsorption capacities of the three adsorbents are the highest. Whereas the adsorption property of multi-functional polymeric adsorbent NJ-99 is the largest
which may be attributed to the strong hydrogen-bonding interaction between the amino groups on the resin and the carboxyl group of p-aminobenzoic acid. The trend of the adsorption capacities of the three adsorbents towards p-aminobenzoic acid with the solution pH is in accord with the dissociation curve of the neutral molecular p-aminobenzoic acid. The adsorption forces includeπ-πinteraction
hydrogen-bonding interaction and electrostatic attraction or repulsion when there exist the molecular and ionic adsorbing species at different pHs in aqueous solution.
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