EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS
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EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS
EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS
高分子科学(英文版)2006年第1期 页码:35-40
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中图分类号:O631.3
纸质出版:2006
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[1].EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS[J].Chinese Journal of Polymer Science,2006(01):35-40.
EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS[J]. 2006, (1): 35-40.
[1].EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS[J].Chinese Journal of Polymer Science,2006(01):35-40.DOI:
EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS[J]. 2006, (1): 35-40.DOI:
EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS
A new kind of binary hydrogels composed of poly(dimethylaminoethylmethacrylate)(PDMAEMA)and poly(ethylene oxide)(PEO)with varying weight average molecular weights((?)
w
=5×10
4
1×10
5
and 2.5×10
6
)were prepared by γ-irradiation technology.The properties of PDMAEMA/PEO hydrogels obtained were evaluated in terms of gel fraction
gel strength
thermal characterization and swelling behavior.The gel strength and swelling degree of the hydrogels could be improved obviously after adding PEO into the PDMAEMA system
while the degree of improvement decreased with increasing (?)
w
of PEO.The temperature sensitivity of PDMAEMA/PEO was retained only in the sample with PEO of (?)
w
=5×10
4
and the pH sensitivity was retained in samples with PEO of (?)
w
=5×10
4
and 1×10
5
.When DMAEMA/PEO mixtures containing PEO of (?)
w
=5×10
4
were irradiated
the main reaction could be the cross-linking of DMAEMA
and the linear PEO molecular chains could penetrate into the cross-linked network of PDMAEMA.With increasing (?)
w
of PEO
some side reactions were induced
such as grafting of DMAEMA onto PEO molecules
the scission or cross-linking of PEO.
Abstract
A new kind of binary hydrogels composed of poly(dimethylaminoethylmethacrylate)(PDMAEMA)and poly(ethylene oxide)(PEO)with varying weight average molecular weights((?)
w
=5×10
4
1×10
5
and 2.5×10
6
)were prepared by γ-irradiation technology.The properties of PDMAEMA/PEO hydrogels obtained were evaluated in terms of gel fraction
gel strength
thermal characterization and swelling behavior.The gel strength and swelling degree of the hydrogels could be improved obviously after adding PEO into the PDMAEMA system
while the degree of improvement decreased with increasing (?)
w
of PEO.The temperature sensitivity of PDMAEMA/PEO was retained only in the sample with PEO of (?)
w
=5×10
4
and the pH sensitivity was retained in samples with PEO of (?)
w
=5×10
4
and 1×10
5
.When DMAEMA/PEO mixtures containing PEO of (?)
w
=5×10
4
were irradiated
the main reaction could be the cross-linking of DMAEMA
and the linear PEO molecular chains could penetrate into the cross-linked network of PDMAEMA.With increasing (?)
w
of PEO
some side reactions were induced
such as grafting of DMAEMA onto PEO molecules
the scission or cross-linking of PEO.
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