ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS
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ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS
ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS
高分子科学(英文版)2006年第1期 页码:73-80
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This study was funded by the National Natural Science Foundation of China(No.20274017)the Natural Science Foundation of Jiangsu Province(No.BK2004415).()
DOI:
中图分类号:O647.31
纸质出版:2006
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[1].ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS[J].Chinese Journal of Polymer Science,2006(01):73-80.
ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS[J]. 2006, (1): 73-80.
[1].ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS[J].Chinese Journal of Polymer Science,2006(01):73-80.DOI:
ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS[J]. 2006, (1): 73-80.DOI:
ADSORPTION OF LATERALLY INTERACTING 1-NAPHTHOL/1-NAPHTHYL-AMINE MIXTURES ON NONPOLAR SURFACES FROM AQUEOUS SOLUTIONS
<正>The binary adsorption behavior of 1-naphthol/1-naphthylamine mixtures in water on nonpolar adsorbent Amberlite XAD4 was investigated at 293 K
303 K and 313 K
respectively.The experimental uptakes of 1-naphthol and l-naphthylamine in all binary-component systems of different molar ratios were obviously higher than the corresponding uptakes predicted by the extended Langmuir model
assuming no interaction between the adsorbed molecules of the two components.This phenomenon was attributed to the cooperative adsorption effect arising from the hydrogen bonding interaction between l-naphthol and l-napbthylamine molecules.A modified extended Langmuir model was proposed to describe the binary adsorption behavior by means of introducing a fitting parameter related with the cooperative adsorption effect of the adsorbates.
Abstract
The binary adsorption behavior of 1-naphthol/1-naphthylamine mixtures in water on nonpolar adsorbent Amberlite XAD4 was investigated at 293 K
303 K and 313 K
respectively.The experimental uptakes of 1-naphthol and l-naphthylamine in all binary-component systems of different molar ratios were obviously higher than the corresponding uptakes predicted by the extended Langmuir model
assuming no interaction between the adsorbed molecules of the two components.This phenomenon was attributed to the cooperative adsorption effect arising from the hydrogen bonding interaction between l-naphthol and l-napbthylamine molecules.A modified extended Langmuir model was proposed to describe the binary adsorption behavior by means of introducing a fitting parameter related with the cooperative adsorption effect of the adsorbates.
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