H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE

Guan-qun Zhong; Qing-hua Duan; Kui-lin Deng; Ai-qin Zhang; Ping Xie; Hai-liang Zhang and Rong-ben Zhang a Institute of Polymer Science; Xiangtan University; Xiangtan 411105; China b State Key Laboratory on Polymer Physics & Chemistry; Joint Laboratory of Polymer Science & Materials; Institute of Chemistry; Chinese Academy of Sciences; Beijing 100080; China c College of Chemistry & Environmental Science; Hebei University; Baoding 071002; China

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H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE

Updated：2021-06-21

- H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE
- H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE
- 高分子科学（英文版） 2006年第1期页码：67-72
- Affiliations：
- Author bio：
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China（Nos.50073028,29974036,20174047）.()
- DOI：
  中图分类号： O631.3
- 纸质出版：2006
- Accepted：
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[1].H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE[J].Chinese Journal of Polymer Science,2006(01):67-72.

H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE[J]. 2006, (1): 67-72.
[1].H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE[J].Chinese Journal of Polymer Science,2006(01):67-72. DOI：

H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE[J]. 2006, (1): 67-72. DOI：

摘要

正

A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane（ALPHS）was first synthesized by an amido H-bonding self-assembled template.ALPHS with molecular weight （?）

=18300 has very highly ordered ladderlike structure

which was confirmed by a sharp resonance absorption peak of[—Si（H）O

2/2

]moiety with the half peak width Δ

1/2

＜0.5 in

Si-NMR spectrum.Presence of the reactive Si—H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si—H reactions such as hydrosilylation

condensation

and so on.

Abstract

A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane（ALPHS）was first synthesized by an amido H-bonding self-assembled template.ALPHS with molecular weight （?）

=18300 has very highly ordered ladderlike structure

which was confirmed by a sharp resonance absorption peak of[—Si（H）O

2/2

]moiety with the half peak width Δ

1/2

＜0.5 in

Si-NMR spectrum.Presence of the reactive Si—H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si—H reactions such as hydrosilylation

condensation

and so on.

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