EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION
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EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION
EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION
高分子科学(英文版)2006年第6期 页码:585-591
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This work was supported by the Jiangsu Province Hi-Tech Fund (GB2003030)Jiangsu Province Natural Science Fund (No. 2004088).()
DOI:
中图分类号:X703;O647.31
纸质出版:2006
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[1].EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION[J].Chinese Journal of Polymer Science,2006(06):585-591.
Guan-hua Meng, Ai-min Li, Wei-ben Yang, et al. EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION[J]. 2006, (6): 585-591.
[1].EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION[J].Chinese Journal of Polymer Science,2006(06):585-591.DOI:
Guan-hua Meng, Ai-min Li, Wei-ben Yang, et al. EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION[J]. 2006, (6): 585-591.DOI:
EFFECT OF HYPERCROSSLINKED RESINS SURFACE CHEMISTRY ON THE ADSORPTION OF PHENOL FROM AQUEOUS SOLUTION
<正>Two hypercrosslinked resins with similar physical characters but different surface chemistry were synthesized and used to remove phenol from aqueous solutions. The FTIR spectra
elemental analysis and the Boehm titration were used to characterize the chemical properties of the resins. The adsorption experiments were carried out using the bottle-point technique
and the effects of the surface chemistry on the adsorption were discussed. The adsorption data fit well with the Freundlich model
indicating the heterogeneity of the resins surface. It could be seen from the experimental results that the adsorption capacity increased with the increase in the total surface concentration of oxygen-containing groups. The pH dependence and the effects of ionic strength were also discussed. The kinetic adsorption data fit well with the pseudo-second order model
and the results showed that the surface oxygen-containing groups have little effect on the adsorption rate.
Abstract
Two hypercrosslinked resins with similar physical characters but different surface chemistry were synthesized and used to remove phenol from aqueous solutions. The FTIR spectra
elemental analysis and the Boehm titration were used to characterize the chemical properties of the resins. The adsorption experiments were carried out using the bottle-point technique
and the effects of the surface chemistry on the adsorption were discussed. The adsorption data fit well with the Freundlich model
indicating the heterogeneity of the resins surface. It could be seen from the experimental results that the adsorption capacity increased with the increase in the total surface concentration of oxygen-containing groups. The pH dependence and the effects of ionic strength were also discussed. The kinetic adsorption data fit well with the pseudo-second order model
and the results showed that the surface oxygen-containing groups have little effect on the adsorption rate.
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