CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE

张榕本

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CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE

Updated：2021-06-21

- CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE
- CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE
- 高分子科学（英文版） 2006年第5期页码：539-544
- Affiliations：
  
  Polym. Chem. Lab. Chinese Academy of Sciences & China Petro-Chemical Corp.), State Key Laboratory on Polymer Physics & Chemistry, Joint Laboratory of Polymer Science & Materials Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China Graduate School of the Chinese Academy of Sciences, Beijing 100039, China College of Chemistry & Environmental Science, Hebei University
- Author bio：
- Funds：
  
  This work was financially supported by NSFC （Nos. 50073028, 29974036 and 20174047）.()
- DOI：
  中图分类号： O631.3
- 纸质出版：2006
- Accepted：
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[1]张榕本.CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE[J].Chinese Journal of Polymer Science,2006(05):539-544.

Kui-lin Deng. CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE[J]. 2006, (5): 539-544.
[1]张榕本.CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE[J].Chinese Journal of Polymer Science,2006(05):539-544. DOI：

Kui-lin Deng. CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE[J]. 2006, (5): 539-544. DOI：

摘要

<正>A novel soluble regular ladder poly（benzoyl-3-aminopropyl） silsesquioxane （LPBAS） was facilely prepared under effective assistance of concerted H-bonding self-assembly of amido groups of side chains and silanol groups

respectively

of a new template monomer [1

3-bis（benzoyl-3-aminopropyl）-1

3-tetraethoxydisiloxane] （M）. The ordered ladder structure of LPBAS is manifested in: （1） the presence of two Bragg peaks representing the ladder width （d） and ladder thickness （t） in X-ray diffraction （XRD） pattern; （2） narrow base-line width （w = 6） of resonance absorption for -CH2SiO3/2 moiety in 29Si-NMR and （3） high glass transition temperature Tg = 112℃in differential scanning calorimetry （DSC） analysis.

Abstract

A novel soluble regular ladder poly（benzoyl-3-aminopropyl） silsesquioxane （LPBAS） was facilely prepared under effective assistance of concerted H-bonding self-assembly of amido groups of side chains and silanol groups

respectively

of a new template monomer [1

3-bis（benzoyl-3-aminopropyl）-1

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