EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING
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EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING
EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING
高分子科学(英文版)2006年第4期 页码:379-387
Affiliations:
Department of Polymer Science & Materials Sichuan University State Key Laboratory of Polymer Materials Engineering Chengdu China,610065
Author bio:
Funds:
This work was financially supported by the National Natural Science Foundation of China (Nos. 20404008, 50373030 and 20490220) the Ministry of Education of China (No. 104154).()
DOI:
中图分类号:TQ320.1
纸质出版:2006
Accepted:
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[1]傅强.EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING[J].Chinese Journal of Polymer Science,2006(04):379-387.
EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING[J]. 2006, (4): 379-387.
[1]傅强.EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING[J].Chinese Journal of Polymer Science,2006(04):379-387.DOI:
EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING[J]. 2006, (4): 379-387.DOI:
EFFECT OF COMPATIBILITY ON PHASE MORPHOLOGY AND ORIENTATION OF ISOTACTIC POLYPROPYLENE (IPP) BLENDS OBTAINED BY DYNAMIC PACKING INJECTION MOLDING
<正>The effect of compatibility on phase morphology and orientation of isotactic polypropylene (iPP) blends under shear stress was investigated via dynamic packing injection molding (DPIM). The compatibility of i’PP blended with other polymers
namely
atactic polypropylene (iPP)
octane-ethylene copolymer (POE)
ethylene-propylene-diene rubber (EPDM) and poly(ethylene-co-vinyl acetate) (EVA)
have first been studied using dynamic mechanical analysis (DMA). These blends were subjected to DPIM
which relies on the application of shear stress fields to the melt/solid interfaces during the packing stage by means of hydraulically actuated pistons. The phase morphology
orientation and mechanical properties of the injection-molded samples were characterized by SEM
2D WAXS and Instron. For incompatible iPP/EVA blends
a much elongated and deformed EVA particles and a higher degree of iPP chain orientation were observed under the effect of shear. However
for compatible iPP/aPP blends
a less deformed and elongated aPP particles and less oriented iPP chains were deduced. It can be concluded that the compatibility between the components decreases the deformation and orientation in the polymer blends. This is most likely due to the hindering effect
resulting from the molecular entanglement and interaction in the compatible system.
Abstract
The effect of compatibility on phase morphology and orientation of isotactic polypropylene (iPP) blends under shear stress was investigated via dynamic packing injection molding (DPIM). The compatibility of i’PP blended with other polymers
namely
atactic polypropylene (iPP)
octane-ethylene copolymer (POE)
ethylene-propylene-diene rubber (EPDM) and poly(ethylene-co-vinyl acetate) (EVA)
have first been studied using dynamic mechanical analysis (DMA). These blends were subjected to DPIM
which relies on the application of shear stress fields to the melt/solid interfaces during the packing stage by means of hydraulically actuated pistons. The phase morphology
orientation and mechanical properties of the injection-molded samples were characterized by SEM
2D WAXS and Instron. For incompatible iPP/EVA blends
a much elongated and deformed EVA particles and a higher degree of iPP chain orientation were observed under the effect of shear. However
for compatible iPP/aPP blends
a less deformed and elongated aPP particles and less oriented iPP chains were deduced. It can be concluded that the compatibility between the components decreases the deformation and orientation in the polymer blends. This is most likely due to the hindering effect
resulting from the molecular entanglement and interaction in the compatible system.
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