ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS
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ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS
ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS
高分子科学(英文版)2006年第3期 页码:237-244
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Author bio:
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This work was supported by the National Natural Science Foundation of China (Nos. 20174036, 20274040, 20574052)the Program for New Century Excellent Talents in University (NCET)the Natural Science Foundation of Zhejiang Province(No. R404047)()
DOI:
中图分类号:O647.31
纸质出版:2006
Accepted:
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[1].ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS[J].Chinese Journal of Polymer Science,2006(03):237-244.
Jia-ye Su, Jin Chen, Zhao-yun Zhang and Lin-xi Zhang Department of Physics, et al. ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS[J]. 2006, (3): 237-244.
[1].ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS[J].Chinese Journal of Polymer Science,2006(03):237-244.DOI:
Jia-ye Su, Jin Chen, Zhao-yun Zhang and Lin-xi Zhang Department of Physics, et al. ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS[J]. 2006, (3): 237-244.DOI:
ADSORPTION OF SHORT TWO-DIMENSIONAL COMPACT CHAINS
<正>Short two-dimensional compact chains adsorbed on the attractive surface at different temperatures were investigated by using the enumeration calculation method. First we investigate the chain size and shape of adsorbed chains
such as characteristic ratios of mean-square radii of gyration <S2>x/N and <S2>y/N
shape factor <δ>
and the orientation of chain bonds <cos2θ> to illuminate how the size and shape of adsorbed compact chains change with increasing temperatures. There are some special behaviors for the chain size and shape at low temperature
especially for strong attraction interaction. In the meantime
adsorbed compact chains have different behaviors from general adsorbed polymer chains. Some thermodynamics properties are also discussed here. Heat capacity changes non-monotonously
first increases and then reduces. The transition temperature Tc is nearly 1.0
1.4
2.0 and 4.2 (in the unit of T0) for the case ofε= 0
-1
-2 and -4 (in the unit of kT0)
respectively. Average energy per bond increases while average Helmholtz free energy per bond decreases with increasing temperatures. From these two thermodynamics parameters we can also get another transition temperature Tc’
and it is close to 0.7
1.1
1.5 and 3.4 forε= 0
-1
-2
and -4
respectively. Therefore
Tc is greater than Tc’ under the same condition. These investigations may provide some insights into the thermodynamics behaviors of adsorbed protein-like chains.
Abstract
Short two-dimensional compact chains adsorbed on the attractive surface at different temperatures were investigated by using the enumeration calculation method. First we investigate the chain size and shape of adsorbed chains
such as characteristic ratios of mean-square radii of gyration <S2>x/N and <S2>y/N
shape factor <δ>
and the orientation of chain bonds <cos2θ> to illuminate how the size and shape of adsorbed compact chains change with increasing temperatures. There are some special behaviors for the chain size and shape at low temperature
especially for strong attraction interaction. In the meantime
adsorbed compact chains have different behaviors from general adsorbed polymer chains. Some thermodynamics properties are also discussed here. Heat capacity changes non-monotonously
first increases and then reduces. The transition temperature Tc is nearly 1.0
1.4
2.0 and 4.2 (in the unit of T0) for the case ofε= 0
-1
-2 and -4 (in the unit of kT0)
respectively. Average energy per bond increases while average Helmholtz free energy per bond decreases with increasing temperatures. From these two thermodynamics parameters we can also get another transition temperature Tc’
and it is close to 0.7
1.1
1.5 and 3.4 forε= 0
-1
-2
and -4
respectively. Therefore
Tc is greater than Tc’ under the same condition. These investigations may provide some insights into the thermodynamics behaviors of adsorbed protein-like chains.
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