SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION

Bo-yong Xue; Kenichi Ogata; Akinori Toyota

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SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION

Papers | Updated：2021-06-21

- SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION
- SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION
- 高分子科学（英文版） 2008年26卷第5期页码：525-531
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- 纸质出版：2008-09-20
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Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 高分子科学（英文版）, 2008,26(5):525-531.

Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 2008, 26(5): 525-531.
Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 高分子科学（英文版）, 2008,26(5):525-531. DOI：

Bo-yong Xue, Kenichi Ogata, Akinori Toyota. SYNTHESIS OF NOVEL BI-FUNCTIONAL COPOLYMER BEARING STERICALLY HINDERED PHENOL AND HINDERED AMINE GROUPS VIA RING-OPENING METATHESIS POLYMERIZATION[J]. 2008, 26(5): 525-531. DOI：

摘要

Norbornene derivatives exo

endo-2-[2-(3

5-di-tert-butyl-4-hydroxyphenoxy)-acetoxy]methyl-5-norbornene (M1) and 3

5-tetramethyl-4-piperidinyl 5-norbornene-exo

endo-2-carboxylate (M2) were synthesized and polymerized by RuCl2(＝CHPh)(PCy3)2 to prepare a novel kind of bi-functional polymer bearing sterically hindered phenol (SHP) and hindered amine (HLAS) groups via ring-opening metathesis polymerization (ROMP). The resulting copolymers were characterized by gel permeation chromatography (GPC)

1H-NMR and differential scanning calorimetry (DSC). The number average molecular weight (Mn) and functional unit content of the resulting copolymer could be regulated by varying the concentration of catalyst and monomer feed.

Abstract

Norbornene derivatives exo

endo-2-[2-(3

5-di-tert-butyl-4-hydroxyphenoxy)-acetoxy]methyl-5-norbornene (M1) and 3

5-tetramethyl-4-piperidinyl 5-norbornene-exo

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