PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION

He-xin Zhang; Ho-young Lee; Young-jun Shin; Dong-ho Lee

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PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION

Papers | Updated：2021-06-21

- PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION
- PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION
- 高分子科学（英文版） 2008年26卷第5期页码：533-537
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- 纸质出版：2008-09-20
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He-xin Zhang, Ho-young Lee, Young-jun Shin, 等. PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION[J]. 高分子科学（英文版）, 2008,26(5):533-537.

He-xin Zhang, Ho-young Lee, Young-jun Shin, et al. PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION[J]. 2008, 26(5): 533-537.
He-xin Zhang, Ho-young Lee, Young-jun Shin, 等. PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION[J]. 高分子科学（英文版）, 2008,26(5):533-537. DOI：

He-xin Zhang, Ho-young Lee, Young-jun Shin, et al. PREPARATION AND PROPERTIES OF MMA/1-PROPYLMETHACRYLATE-POSS COPOLYMER WITH ATOM TRANSFER RADICAL POLYMERIZATION[J]. 2008, 26(5): 533-537. DOI：

摘要

The methyl methacrylate (MMA)/1-propylmethacrylate-polyhedral oligomeric silsesquioxane (PM-POSS) copolymers were synthesized via atom transfer radical polymerization with CuBr as catalyst. The unreacted PM-POSS monomer could be removed completely by washing the copolymerization product with n-hexane. The copolymers were characterized with 1H-NMR

X-ray diffraction

differential scanning calorimetry

thermogravimetric analysis and gel permeation chromatography. With increasing PM-POSS feed ratio

the total conversion increased while the glass transition temperatures of copolymer decreased. The thermogravimetric analysis demonstrated that the thermal stability of copolymer improved slightly with PM-POSS addition. The molecular weight of copolymers increased with incorporation of PM-POSS.

Abstract

X-ray diffraction

differential scanning calorimetry

thermogravimetric analysis and gel permeation chromatography. With increasing PM-POSS feed ratio

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