STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS
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STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS
STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS
高分子科学(英文版)2008年26卷第6期 页码:759-766
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纸质出版:2008-11-20
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Hong-ge Tan a, Zi-yu Wang b, Wen-fang Zhu a, 等. STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS[J]. 高分子科学(英文版), 2008,26(6):759-766.
Hong-ge Tan a, Zi-yu Wang b, Wen-fang Zhu a, et al. STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS[J]. 2008, 26(6): 759-766.
Hong-ge Tan a, Zi-yu Wang b, Wen-fang Zhu a, 等. STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS[J]. 高分子科学(英文版), 2008,26(6):759-766.DOI:
Hong-ge Tan a, Zi-yu Wang b, Wen-fang Zhu a, et al. STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS[J]. 2008, 26(6): 759-766.DOI:
STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS
the structure evolution of the hexagonal cylindrical phase of diblock copolymers in films was investigated. Employing the Landau-Brazovskii mean field theory
we obtained three amplitude parameters as functions of temperature
surface field strength and film thickness. By controlling confinement size and surface field strength
lamellae and undulated lamellae appear in the cylindrical bulk phase of diblock copolymers. “Phase diagrams” of confinement-induced structures are constructed at different surface field strengths. The obtained theoretical results are in agreement with relevant theoretical and experimental results.
Abstract
In the weak segregation limit
the structure evolution of the hexagonal cylindrical phase of diblock copolymers in films was investigated. Employing the Landau-Brazovskii mean field theory
we obtained three amplitude parameters as functions of temperature
surface field strength and film thickness. By controlling confinement size and surface field strength
lamellae and undulated lamellae appear in the cylindrical bulk phase of diblock copolymers. “Phase diagrams” of confinement-induced structures are constructed at different surface field strengths. The obtained theoretical results are in agreement with relevant theoretical and experimental results.
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