MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED

Yu-zeng Zhao; Xin-lin Yang; Wen-qiang Huang

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MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED

Papers | Updated：2021-06-21

- MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED
- MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED
- 高分子科学（英文版） 2005年23卷第3期页码：235-242
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- 纸质出版：2005-05-20
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Yu-zeng Zhao, Xin-lin Yang, Wen-qiang Huang. MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED[J]. 高分子科学（英文版）, 2005,23(3):235-242.

Yu-zeng Zhao, Xin-lin Yang, Wen-qiang Huang. MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED[J]. 2005, 23(3): 235-242.
Yu-zeng Zhao, Xin-lin Yang, Wen-qiang Huang. MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED[J]. 高分子科学（英文版）, 2005,23(3):235-242. DOI：

Yu-zeng Zhao, Xin-lin Yang, Wen-qiang Huang. MICRON CORE-SHELL PARTICLES PREPARED BY GRAFTING POLYMERIZATION OF METHYL METHACRYLATE FROM NARROW DISPERSE SURFACE OF CHLOROMETHYLATED[J]. 2005, 23(3): 235-242. DOI：

摘要

Grafting of poly(methyl methacrylate) from narrow disperse polymer particles by surface-initiated atom transfer radical polymerization (ATRP) was investigated. Polydivinylbenzene (PDVB) particles were prepared by dispersion polymerization with poly(N-vinyl pyrrolidone) (PVP) as the stabilizer. Chloromethylated PDVB was used as initiating core sites for subsequent ATRP of methyl methacrylate with CuBr/bpy as catalyst system. It was found that poly(methyl methacrylate) was grafted not only from the particle surfaces but also from within a thin shell layer

leading to particles size increases from 2.38-3.00 μm with a core-shell structure particles. The grafted core-shell particles were characterized with FTIR

SEM

DSC.

Abstract

leading to particles size increases from 2.38-3.00 μm with a core-shell structure particles. The grafted core-shell particles were characterized with FTIR

SEM

DSC.

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