RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS

Feng-en Chen; Ming-xiao Fu; Fan Wang; Bin Fan; Gao-quan Shi

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RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS

Note | Updated：2021-06-21

- RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS
- RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS
- 高分子科学（英文版） 2005年23卷第6期页码：681-685
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- 纸质出版：2005-11-20
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Feng-en Chen, Ming-xiao Fu, Fan Wang, 等. RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS[J]. 高分子科学（英文版）, 2005,23(6):681-685.

Feng-en Chen, Ming-xiao Fu, Fan Wang, et al. RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS[J]. 2005, 23(6): 681-685.
Feng-en Chen, Ming-xiao Fu, Fan Wang, 等. RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS[J]. 高分子科学（英文版）, 2005,23(6):681-685. DOI：

Feng-en Chen, Ming-xiao Fu, Fan Wang, et al. RAMAN SPECTROSCOPIC STUDY ON THE CHAIN CONFORMATION OF ELECTROSYNTHESIZED POLY(P-PHENYLENE) FILMS[J]. 2005, 23(6): 681-685. DOI：

摘要

Poly(p-phenylene) (PPP) films have been electrochemically deposited on mirrorlike stainless steel (SS) electrode surfaces by direct oxidation of benzene in boron trifluoride diethyl etherate (BFEE) solutions at a constant applied potential of 1.7 V (versus Ag/AgCl). The chain conformations of as-grown PPP films have been studied by Raman spectroscopy. The results demonstrated that high synthesis temperature favors the formation of planar PPP

and the conformation of planar PPP can be changed into torsional PPP by cooling treatment.

Abstract

and the conformation of planar PPP can be changed into torsional PPP by cooling treatment.

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