OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION

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OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION

Papers | Updated：2021-06-21

- OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION
- OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION
- 高分子科学（英文版） 2004年22卷第3期页码：253-258
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- 纸质出版：2004-06-20
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OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION[J]. 高分子科学（英文版）, 2004,22(3):253-258.

OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION[J]. 2004, 22(3): 253-258.
OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION[J]. 高分子科学（英文版）, 2004,22(3):253-258. DOI：

OPTIMIZATION OF THE SYNTHESIS OF ACRYLAMIDE HYDROGEL BY γ-RAY IRRADIATION[J]. 2004, 22(3): 253-258. DOI：

摘要

Hydrogels have been synthesized from 10%

20%

30%

40%

50% and 60% aqueous solutions of acrylamide monomer by gamma radiation employing doses in the range of 0.2-30 kGy from a Co-60 source. The effect of solution concentration

γ-ray dose

pH and time was studied in order to observe the optimizing conditions in the characterization of hydrogels. Gel fraction increases with dose for all concentrations indicating hundred-percentage conversion of gel at doses≥ 5 kGy for homogenous solutions in the range of 20%-50% concentration. On the other hand

10% solution provides conversion less than 86% even at 30 kGy

whereas 60% monomer makes an inhomogeneous solution which stile gives about 100% gel fraction. Swelling of hydrogels under water with respect to time varies with both the doses and concentrations due to the change of crosslinking density in the gels. The maximum volume change of hydrogels during swelling and water desorption mainly occurs within 24 h. Swelling is also enhanced with the rise of pH due to change of ionic content of the solvent. Considering the amount of gel fraction and the properties of hydrogel

the samples prepared from 20% solution at 5 kGy show better results. Moreover

the effect of bacteria on hydrogel was found to be nil

suggesting a prohibition of growth of microorganism in it.

Abstract

Hydrogels have been synthesized from 10%

20%

30%

40%

50% and 60% aqueous solutions of acrylamide monomer by gamma radiation employing doses in the range of 0.2-30 kGy from a Co-60 source. The effect of solution concentration

γ-ray dose

10% solution provides conversion less than 86% even at 30 kGy

the samples prepared from 20% solution at 5 kGy show better results. Moreover

the effect of bacteria on hydrogel was found to be nil

suggesting a prohibition of growth of microorganism in it.

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