GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION

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GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION

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- GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION
- GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION
- 高分子科学（英文版） 2003年21卷第1期页码：51-56
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- 纸质出版：2003-02-20
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GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION[J]. 高分子科学（英文版）, 2003,21(1):51-56.

GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION[J]. 2003, 21(1): 51-56.
GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION[J]. 高分子科学（英文版）, 2003,21(1):51-56. DOI：

GRAFTING OF ETHYLENE GLYCOL DIMETHACRYLATE ONTO SILK IN AQUEOUS ALCOHOLIC SOLUTION[J]. 2003, 21(1): 51-56. DOI：

摘要

The grafting of ethylene glycol dimethacrylate (EGDMA) onto silk in aqueous alcohol systems using potassiumpersulfate (KPS) in the presence of air was investigated. Effects of grafting conditions

such as concentrations of monomer

initiator and formic acid

temperature and time

on the graft yield were determined. The optimum graft conditions were foundto be: T = 80℃

t = 30 min

[KPS] = 1.85% [on the weight ofmonomer (owm)]; [formic acid] = 0.2% (V/V); [EGDMA] =80% [on the weight of fiber(owf)].The activation energy of grafting at 50-80℃ was found to be 71.31 kJ/mol for EGDMA.Grafting equations were also evaluated.The graft yield value can be regulated by the concentration of monomer.The graft copolymerization of EFDMA onto silk is effective in improving the crease-proofing of silk fabrics.

Abstract

The grafting of ethylene glycol dimethacrylate (EGDMA) onto silk in aqueous alcohol systems using potassiumpersulfate (KPS) in the presence of air was investigated. Effects of grafting conditions

such as concentrations of monomer

initiator and formic acid

temperature and time

on the graft yield were determined. The optimum graft conditions were foundto be: T = 80℃

t = 30 min

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