MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS

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MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS

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- MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS
- MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS
- 高分子科学（英文版） 2002年20卷第6期页码：537-541
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- 纸质出版：2002-12-20
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MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS[J]. 高分子科学（英文版）, 2002,20(6):537-541.

MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS[J]. 2002, 20(6): 537-541.
MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS[J]. 高分子科学（英文版）, 2002,20(6):537-541. DOI：

MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS[J]. 2002, 20(6): 537-541. DOI：

摘要

Polysiloxane bearing pendant quaternary ammonium groups (PSI) was used to modify the surface properties ofepoxy resins. In the cured resin

PSI formed the dispersed phase. Remarkable enrichment and gradient distribution ofpolysiloxane on the surface region of the epoxy resins were demonstrated by XPS analysis. The composition and propertiesof the surface of PSI-modified epoxy resin

which is in contact with the mold

are dependent on the material of the mold.Through the incorporation of PSI

epoxy resins with low surface energy and low friction coefficient were obtained.Polysiloxane with lower ionic group content shows a higher degree of enrichment on the resin surface and leads to a higher contact angle against water

while the polysiloxane having optimum compatibility with the epoxy resin shows a greater effect in reducing the static friction coefficient of the resin against glass.

Abstract

Polysiloxane bearing pendant quaternary ammonium groups (PSI) was used to modify the surface properties ofepoxy resins. In the cured resin

which is in contact with the mold

are dependent on the material of the mold.Through the incorporation of PSI

while the polysiloxane having optimum compatibility with the epoxy resin shows a greater effect in reducing the static friction coefficient of the resin against glass.

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