A series of cellulose acetate membranes were prepared by using formamide as additive
and then were hydrolyzedin 4 wt% aqueous NaOH solution for 8 h to obtain regenerated cellulose membranes. The dependence of degree ofsubstitution
structure
porous properties
solubility and thermal stability on hydrolysis time was studied by chemical titration
Fourier transform infrared spectroscopy
scanning electron microscopy
wide-angle X-ray diffraction
and differential scanning calorimetry
respectively.The results indicated that the pore size of the regenerated cellulose membranes was slightly smaller than that of cellulose acetate membrane
while solvent-resistance
crystallinity and thermostability were significantly improved.This work provides a simple way to prepare the porous cellulose membranes
which not only kept the good pore characteristics of cellulose acetate membranes
but also possessed solvent-resistance
high crystallinity and thermostability.Therefore
the application range of cellulose acetate membranes can be expanded.
Abstract
A series of cellulose acetate membranes were prepared by using formamide as additive
and then were hydrolyzedin 4 wt% aqueous NaOH solution for 8 h to obtain regenerated cellulose membranes. The dependence of degree ofsubstitution
structure
porous properties
solubility and thermal stability on hydrolysis time was studied by chemical titration
Fourier transform infrared spectroscopy
scanning electron microscopy
wide-angle X-ray diffraction
and differential scanning calorimetry
respectively.The results indicated that the pore size of the regenerated cellulose membranes was slightly smaller than that of cellulose acetate membrane
while solvent-resistance
crystallinity and thermostability were significantly improved.This work provides a simple way to prepare the porous cellulose membranes
which not only kept the good pore characteristics of cellulose acetate membranes
but also possessed solvent-resistance
high crystallinity and thermostability.Therefore
the application range of cellulose acetate membranes can be expanded.
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