SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

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SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

Papers | Updated：2021-06-21

- SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*
- SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*
- 高分子科学（英文版） 2002年20卷第2期页码：177-180
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- 纸质出版：2002-04-20
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SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 高分子科学（英文版）, 2002,20(2):177-180.

SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 2002, 20(2): 177-180.
SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 高分子科学（英文版）, 2002,20(2):177-180. DOI：

SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. 2002, 20(2): 177-180. DOI：

摘要

A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1

4-dioxane-2

5-dione (3-BMG). According to this route

3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate

which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.

Abstract

A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1

4-dioxane-2

5-dione (3-BMG). According to this route

3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate

which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.

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