NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*
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NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*
NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*
高分子科学(英文版)2001年19卷第5期 页码:451-454
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纸质出版:2001-10-20
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NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*[J]. 高分子科学(英文版), 2001,19(5):451-454.
NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*[J]. 2001, 19(5): 451-454.
NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*[J]. 高分子科学(英文版), 2001,19(5):451-454.DOI:
NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*[J]. 2001, 19(5): 451-454.DOI:
NOVEL SYNTHESIS OF LONG MULTI-BLOCK HETEROPOLYMER CHAINS WITH AN ORDERED SEQUENCE AND CONTROLLABLE BLOCK LENGTHS*
It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnishing each end ofpolymer blocks with a reactive functional group
one can only prepare heteropolymer chains with few long blocks
such asdiblock and triblock copolymers. The most plausible result so far was a pentablock copolymer. Recently
using a combinationof polymer physics and synthetic chemistry
we have invented self-assembly assisted polycondensation (SAAP).This communication reports the results of using this novel method to connect 10-100 triblock polymer chains together to form long multi-block heteropolymer chains with an ordered sequence and controllable block lengths.
Abstract
It had very long been a dream in polymer science to synthesize long multi-block polymer chains with an orderedchain sequence and controllable block lengths. Using ionic or living free radical polymerization or furnishing each end ofpolymer blocks with a reactive functional group
one can only prepare heteropolymer chains with few long blocks
such asdiblock and triblock copolymers. The most plausible result so far was a pentablock copolymer. Recently
using a combinationof polymer physics and synthetic chemistry
we have invented self-assembly assisted polycondensation (SAAP).This communication reports the results of using this novel method to connect 10-100 triblock polymer chains together to form long multi-block heteropolymer chains with an ordered sequence and controllable block lengths.
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