SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*

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SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*

Papers | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*
- SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*
- 高分子科学（英文版） 2001年19卷第1期页码：1-6
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- 纸质出版：2001-02-20
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SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 高分子科学（英文版）, 2001,19(1):1-6.

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 2001, 19(1): 1-6.
SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 高分子科学（英文版）, 2001,19(1):1-6. DOI：

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS*[J]. 2001, 19(1): 1-6. DOI：

摘要

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer

3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS)

was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane

which has potential application as a precursor for synthesizing advanced functional polymers

was characterized by FTIR

1H-NMR

13C-NMR

29Si-NMR

vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

Abstract

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer

3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS)

was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane

which has potential application as a precursor for synthesizing advanced functional polymers

was characterized by FTIR

1H-NMR

13C-NMR

29Si-NMR

vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

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