SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*

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SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*

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- SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*
- SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*
- 高分子科学（英文版） 2000年18卷第5期页码：459-463
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- 纸质出版：2000-10-20
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SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*[J]. 高分子科学（英文版）, 2000,18(5):459-463.

SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*[J]. 2000, 18(5): 459-463.
SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*[J]. 高分子科学（英文版）, 2000,18(5):459-463. DOI：

SYNTHESIS OF NEW HIGH MOLECULAR WEIGHT AND REACTIVE LADDERLIKE POLYSILSESQUIOXANES*[J]. 2000, 18(5): 459-463. DOI：

摘要

Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization".The molecular weight of CP-T is as high as 1.7×105. It is a tough

elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactivepolysilsesquioxanes

which can be used as potential precursors in the synthesis of functional ladderlike polymers.

Abstract

Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization".The molecular weight of CP-T is as high as 1.7×105. It is a tough

elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactivepolysilsesquioxanes

which can be used as potential precursors in the synthesis of functional ladderlike polymers.

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