COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS
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COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS
COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS
高分子科学(英文版)1999年17卷第2期 页码:141-144
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纸质出版:1999-04-20
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COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS[J]. 高分子科学(英文版), 1999,17(2):141-144.
COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS[J]. 1999, 17(2): 141-144.
COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS[J]. 高分子科学(英文版), 1999,17(2):141-144.DOI:
COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS[J]. 1999, 17(2): 141-144.DOI:
COMONOMER SEQUENCE DISTRIBUTION IN METALLOCENE-BASED ETHYLENE/1-BUTENE (S-34) AND ETHYLENE/1-HEXENE (S-43) COPOLYMERS
Metallocene based polyethylenes were prepared by SINOPEC's "metallocene adduct" technologyin a gas phase fluidized bed model reactor. The 13C-NMR spectra of ethylene/1 -butene (S-34) and ethylene/1-hexene(S-43) copolymers were studied in a manner analogous to that established by Hsieh and Cheng. Thecomonomer sequence distributions of copolymer samples were obtained. The results show that thesemetallocene based copolymers contain a small amount of butene and hexene
and the EE and EEE sequencesare dominant.
Abstract
Metallocene based polyethylenes were prepared by SINOPEC's "metallocene adduct" technologyin a gas phase fluidized bed model reactor. The 13C-NMR spectra of ethylene/1 -butene (S-34) and ethylene/1-hexene(S-43) copolymers were studied in a manner analogous to that established by Hsieh and Cheng. Thecomonomer sequence distributions of copolymer samples were obtained. The results show that thesemetallocene based copolymers contain a small amount of butene and hexene
and the EE and EEE sequencesare dominant.
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