SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*

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SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*

Papers | Updated：2021-06-21

- SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*
- SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*
- 高分子科学（英文版） 1999年17卷第5期页码：441-446
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- 纸质出版：1999-10-20
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SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*[J]. 高分子科学（英文版）, 1999,17(5):441-446.

SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*[J]. 1999, 17(5): 441-446.
SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*[J]. 高分子科学（英文版）, 1999,17(5):441-446. DOI：

SYNTHESIS AND CATALYTIC BEHAVIOR OF POLYSILOXANESUPPORTED FULLERENE PLATINUM OR RHODIUM COMPLEXES*[J]. 1999, 17(5): 441-446. DOI：

摘要

Two polysiloxanes with pendant fullerene moieties and their platinum or rhodium complexes havebeen prepared from C60 via amination with ω-decenylamine

followed by hydrosilylation with triethoxysilaneand immobilization on fumed silica or by hydrosilylation with methyldichlorosilane and polycondensationwith polydimethylsiloxanol

and then by reacting them with potassium chloroplatinite or rhodium chloride inacetone respectively under argon atmosphere. It was found that the four noble metal complexes are effective catalysts for the hydrosilylation of olefins with triethoxysilane.The regioselectivity of platinum complexes for styrene increases remarkably by introducing C60 moiety.Factors influencing catalytic actalytic activity and the mechanism have been investigated.

Abstract

Two polysiloxanes with pendant fullerene moieties and their platinum or rhodium complexes havebeen prepared from C60 via amination with ω-decenylamine

followed by hydrosilylation with triethoxysilaneand immobilization on fumed silica or by hydrosilylation with methyldichlorosilane and polycondensationwith polydimethylsiloxanol

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